An isomer of the endohedral metallofullerene Sc3N@C80 with D5h symmetry

被引：82
|
作者：
Duchamp, JC
Demortier, A
Fletcher, KR
Dorn, D
Iezzi, EB
Glass, T
Dorn, HC
机构：
[1] Emory & Henry Coll, Dept Chem, Emory, VA 24327 USA
[2] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24060 USA
来源：
CHEMICAL PHYSICS LETTERS | 2003年 / 375卷 / 5-6期
关键词：
D O I：
10.1016/S0009-2614(03)00844-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The discovery of a new isomer of the endohedral metallofullerene Sc3N@C-80 is reported. C-13 labeled (similar to9%) Sc3N@C-80 has been synthesized and has been characterized by HPLC, mass spectroscopy and C-13 NMR data. The C-13 NMR spectrum shows six peaks with a 1:2:2:1:1:1 ratio that are assigned to the D-5h isomer. The results of theoretical calculations are also reported for the I-h and D-5h isomers of SC3N@C-80. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：655 / 659
页数：5
相关论文
共 50 条
  • [41] 2-Aminoethanol Extraction as a Method for Purifying Sc3N@C80 and for Differentiating Classes of Endohedral Fullerenes on the Basis of Reactivity
    Sarina, Evan A.
    Mercado, Brandon Q.
    Franco, Jimmy U.
    Thompson, Christopher J.
    Easterling, Michael L.
    Olmstead, Marilyn M.
    Balch, Alan L.
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (47) : 17035 - 17043
  • [42] Orientational Effects on the Electronic Structure and Polarization in Sc3N@C80
    Ashman, Christopher R.
    Halilov, Samed
    JOURNAL OF PHYSICAL CHEMISTRY A, 2022, 126 (10): : 1605 - 1616
  • [43] Effect of copper metal on the yield of Sc3N@C80 metallofullerenes
    Stevenson, Steven
    Mackey, Mary A.
    Thompson, M. Corey
    Coumbe, H. Louie
    Madasu, Praveen K.
    Coumbe, Curtis E.
    Phillips, J. Paige
    CHEMICAL COMMUNICATIONS, 2007, (41) : 4263 - 4265
  • [44] Characterization of the bis-silylated endofullerene Sc3N@C80
    Wakahara, Takatsugu
    Iiduka, Yuko
    Ikenaga, Ozora
    Nakahodo, Tsukasa
    Sakuraba, Akihiro
    Tsuchiya, Takahiro
    Maeda, Yutaka
    Kako, Masahiro
    Akasaka, Takeshi
    Yoza, Kenji
    Horn, Ernst
    Mizorogi, Naomi
    Nagase, Shigeru
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (30) : 9919 - 9925
  • [45] Full Exploration of the Diels-Alder Cycloaddition on Metallofullerenes M3N@C80 (M=Sc, Lu, Gd): The D5h versus Ih Isomer and the Influence of the Metal Cluster
    Osuna, Sillvia
    Valencia, Ramon
    Rodriguez-Fortea, Antonio
    Swart, Marcel
    Sola, Miquel
    Poblet, Josep M.
    CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (29) : 8944 - 8956
  • [46] Endohedral metallofullerene Sc3NC@C84: a theoretical prediction
    Wang, Dong-Lai
    Xu, Hong-Liang
    Su, Zhong-Min
    Xin, Guang
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (43) : 15099 - 15105
  • [47] Endohedral metallofullerene Sc3NC@C82: A theoretical prediction
    Meng, Qing-Ya
    Sun, Xiao-Yuan
    Wang, Cui-Yan
    Wang, Dong-Lai
    CHEMICAL PHYSICS LETTERS, 2014, 613 : 24 - 28
  • [48] Synthesis and Characterization of the D5h Isomer of the Endohedral Dimetallofullerene Ce2@C80: Two-Dimensional Circulation of Encapsulated Metal Atoms Inside a Fullerene Cage
    Yamada, Michio
    Mizorogi, Naomi
    Tsuchiya, Takahiro
    Akasaka, Takeshi
    Nagase, Shigeru
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (37) : 9486 - 9493
  • [49] Persubstituted Triphenylamine Bearing Zinc Porphyrin to Host Endohedral Fullerene, Sc3N@C80: Formation and Excited State Electron Transfer
    Sankar, Muniappan
    Rathi, Pinki
    Ganesan, Ashwin
    Seetharaman, Sairaman
    Karr, Paul A.
    D'Souza, Francis
    JOURNAL OF PHYSICAL CHEMISTRY B, 2020, 124 (27): : 5723 - 5729
  • [50] Electronic structure of pristine and intercalated Sc3N@C80 from photoemission
    Alvarez, L
    Georgi, P
    Schwieger, T
    Dunsch, L
    Pichler, T
    Knupfer, M
    Golden, MS
    Fink, J
    Bressler, P
    Mast, M
    ELECTRONIC PROPERTIES OF MOLECULAR NANOSTRUCTURES, 2001, 591 : 114 - 117
12345