Siloxide Complexes of Chromium(II), Manganese(H), Cobalt(II), and Chromium(III) Incorporating Potassium(I)

被引：9

作者：

Koenig, Sonja N. ^{[1
]}

Maichle-Moessmer, Cacilia ^{[1
]}

Toernroos, Karl W. ^{[2
]}

Anwander, Reiner ^{[1
]}

机构：

[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

[2] Univ Bergen, Dept Chem, N-5007 Bergen, Norway

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2014年 / 69卷 / 11-12期

关键词：

Siloxides; Silylamides; Transition Metals; Alkali Metals; Ate Complexes; STRUCTURAL-CHARACTERIZATION; METATHESIS CATALYSTS; MOLYBDENUM NITRIDE; CRYSTAL-STRUCTURES; ALKYNE METATHESIS; TRANSITION METALS; LITHIUM-CALCIUM; CHEMISTRY; SILICA; REAGENTS;

D O I：

10.5560/ZNB.2014-4167

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Heteroleptic ate complexes of the type K[M{N(SiMe3)(2)}(2){OSi((OBn)-Bn-t)(3)}] (M = Cr, Mn, Co) were synthesized by adding one equivalent of the potassium salt KOSi((OBu)-Bu-t)(3) to the bis(trimethylsilypamide precursors [CrIN(SiMe3)(2)}(2) (thf)(2)], [MnIN(SiMe3)(2)}(2)(thf)] and [Co{N(SiMe3)(2)}(2)(thf)], respectively. Surprisingly, the reaction of CrCl3(thf)(3) with only two equivalents of KOSi((OBu)-Bu-t)(3) yielded the homoleptic ate complex K[CrtOSi((OBu)-Bu-t)(3)}(4)]. The compounds were characterized by elemental analysis and DRIFT spectroscopy as well as X-ray crystallography.

引用

页码：1375 / 1383

页数：9

共 50 条

[41] CHROMIUM(II) AND VANADIUM(II) REDUCTION OF PENTACYANOCOBALTATE(III) COMPLEXES
BALAHURA, RJ
JOHNSON, MD
[J]. INORGANIC CHEMISTRY, 1989, 28 (25) : 4548 - 4551
[42] THE CHROMIUM(II) AND VANADIUM(II) REDUCTION OF PENTACYANOCOBALTATE(III) COMPLEXES
JOHNSON, MD
BALAHURA, RJ
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 197 : 284 - INOR
[43] CHROMIUM(II) AND CHROMIUM(III) COMPLEXES CONTAINING HYDRAZINES OR HYDRAZINECARBOXYLATES AS LIGANDS
EDWARDS, DA
THOMPSETT, D
BELLERBY, JM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (11): : 1761 - 1767
[44] COMPLEXES OF TETRAHYDROTHIAMINE AND ITS PHOSPHATE-ESTERS WITH CHROMIUM(III), IRON(III), COBALT(II), NICKEL(II) AND COPPER(II)
HADJILIADIS, N
YANNOPOULOS, A
DEGRAVE, E
BAU, R
[J]. BULLETIN DES SOCIETES CHIMIQUES BELGES, 1989, 98 (04): : 223 - 235
[45] Adsorption of thallium(I), lead(II), copper(II), bismuth(III) and chromium(III) by electrolytic manganese dioxide
Dahal, MP
Lawrance, GA
[J]. ADSORPTION SCIENCE & TECHNOLOGY, 1996, 13 (04) : 231 - 240
[46] CHROMIUM(II) AND CHROMIUM(III) TRI-TERT-BUTOXYSILOXY COMPLEXES
TERRY, KW
GANTZEL, PK
TILLEY, TD
[J]. INORGANIC CHEMISTRY, 1993, 32 (23) : 5402 - 5404
[47] MOLTEN CALCIUM NITRATE TETRAHYDRATE - SPECTROSCOPY OF CHROMIUM(III), COBALT(II), NICKEL(II) AND COPPER(II) NITRATES AND SOME COMPLEXES OF NICKEL(II) AND COBALT(III)
KERRIDGE, DH
TARIQ, SA
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1993, 46 (06) : 917 - 920
[48] ALKYLENEBISDITHIOCARBAMATES OF OXOVANADIUM(IV), CHROMIUM(III), AND MANGANESE(II)
KWOKA, W
MOYER, RO
LINDSAY, R
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1975, 37 (09): : 1889 - 1892
[49] COMPLEXES OF CHROMIUM(III), MANGANESE(II) AND NICKEL(II) WITH METHYLHYDRAZINECARBOXYLATE AND 1,1-DIMETHYLHYDRAZINECARBOXYLATE LIGANDS
ABDELMAGIED, HA
BELLERBY, JM
[J]. TRANSITION METAL CHEMISTRY, 1994, 19 (02) : 141 - 145
[50] Chromium(III), manganese(II), cobalt(II), nickel(II), copper(II) and palladium(II) complexes of a 12-membered tetraaza [N4] macrocyclic ligand
Sulekh Chandra
Sunil Dutta Sharma
[J]. Transition Metal Chemistry, 2002, 27 : 732 - 735

← 1 2 3 4 5 →