Unprecedented direct conversion of N-N and N=N bonds to N-(tert-butyloxy)-carbamates

被引：0

作者：

Chandrasekhar, S ^{[1
]}

Reddy, CR ^{[1
]}

Rao, RJ ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India

来源：

SYNLETT | 2001年 / 10期

关键词：

polymethylhydrosiloxane; hydrazines; azo compounds; tert-butyl carbamates; one-pot reaction;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

For the first time a one step direct conversion of aromatic hydrazines and azo compounds to N-(tert-butoxycarbonyl) amines is achieved via reductive cleavage of N-N and N=N bonds using the inexpensive and safe hydride source polymethylhydrosiloxane (PMHS) and di-tert-butyl dicarbonate [(Boc)(2)O] in the presence of a catalytic amount of 10% Pd-C.

引用

页码：1561 / 1562

页数：2

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