Unprecedented direct conversion of N-N and N=N bonds to N-(tert-butyloxy)-carbamates

被引：0
|
作者：
Chandrasekhar, S [1 ]
Reddy, CR [1 ]
Rao, RJ [1 ]
机构：
[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India
来源：
SYNLETT | 2001年 / 10期
关键词：
polymethylhydrosiloxane; hydrazines; azo compounds; tert-butyl carbamates; one-pot reaction;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
For the first time a one step direct conversion of aromatic hydrazines and azo compounds to N-(tert-butoxycarbonyl) amines is achieved via reductive cleavage of N-N and N=N bonds using the inexpensive and safe hydride source polymethylhydrosiloxane (PMHS) and di-tert-butyl dicarbonate [(Boc)(2)O] in the presence of a catalytic amount of 10% Pd-C.
引用
收藏
页码：1561 / 1562
页数：2
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