A study of carbonaceous products formed in the thermolysis of tricresyl phosphate, tributyl phosphate, and tributyl phosphite

被引：0

作者：

Pavelko, G. F. ^{[1
]}

Pavelko, R. G. ^{[2
]}

机构：

[1] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow, Russia

[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow, Russia

来源：

PETROLEUM CHEMISTRY | 2011年 / 51卷 / 04期

关键词：

VAPOR-PHASE LUBRICANTS; CARBONS; SURFACE; ACTIVATION; RAMAN;

D O I：

10.1134/S0965544111040050

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The composition and morphology of carbonaceous products formed upon the thermal decomposition of tricresyl phosphate, tributyl phosphate, and tributyl phosphite at a temperature of 760 degrees C in a fused-silica flow reactor have been studied for the first time. It has been shown that they contain P-O-C bonds and are graphite-like clusters with a size of <= 1 nm self-assembled into spherical or fibrous structures.

引用

页码：303 / 307

页数：5

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