A study of carbonaceous products formed in the thermolysis of tricresyl phosphate, tributyl phosphate, and tributyl phosphite

被引：0
|
作者：
Pavelko, G. F. [1 ]
Pavelko, R. G. [2 ]
机构：
[1] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow, Russia
[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow, Russia
来源：
PETROLEUM CHEMISTRY | 2011年 / 51卷 / 04期
关键词：
VAPOR-PHASE LUBRICANTS; CARBONS; SURFACE; ACTIVATION; RAMAN;
D O I：
10.1134/S0965544111040050
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The composition and morphology of carbonaceous products formed upon the thermal decomposition of tricresyl phosphate, tributyl phosphate, and tributyl phosphite at a temperature of 760 degrees C in a fused-silica flow reactor have been studied for the first time. It has been shown that they contain P-O-C bonds and are graphite-like clusters with a size of <= 1 nm self-assembled into spherical or fibrous structures.
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页码：303 / 307
页数：5
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