High-nuclear polyoxovanadates assembled from pentagonal building blocks

被引：15

作者：

Zhang, Ting ^{[1
]}

Hou, Yuhan ^{[1
]}

Hou, Baoshan ^{[1
]}

Zhao, Liang ^{[1
]}

Wang, Xinlong ^{[1
,2
]}

Qin, Chao ^{[1
]}

Su, Zhongmin ^{[1
,2
]}

机构：

[1] Northeast Normal Univ, Key Lab Polyoxometalate & Reticular Mat Chem, Minist Educ, Changchun 130024, Peoples R China

[2] Hainan Univ, Coll Sci, Haikou 570228, Hainan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 79期

关键词：

METAL-ORGANIC POLYHEDRA; OXIDATION; CONSTRUCTION; CATALYST; UNITS; SIZE;

D O I：

10.1039/d2cc04436f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The design and synthesis of high-nuclear polyoxometalates (POMs) constructed from pentagonal molecular building blocks (MBBs) are attractive and challenging. Herein, three new high-nuclear polyoxovanadates, including {V20W2P20} (1), {V18W4P14} (2), and {V26W6P16} (3), have been successfully synthesized under solvothemial conditions. All these structures are assembled from pentagonal MBB {WV5(PhPO3)(5)} with different configurations. Compound 1 exhibits efficient, stable, and versatile catalytic activity for sulfide oxidation.

引用

页码：11111 / 11114

页数：4

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