cis-1,2,3,6-tetrahydrophthalic anhydride at 173 K

被引:4
|
作者
Bolte, M [1 ]
Bauch, C [1 ]
机构
[1] Univ Frankfurt, Inst Organ Chem, D-60439 Frankfurt, Germany
关键词
D O I
10.1107/S0108270198012402
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, C8H8O3, (I), crystallizes with two nearly identical molecules in the asymmetric unit. Each molecule has a boat conformation and noncrystallographic mirror symmetry. The structure was determined in connection with a study of the possible chemical decomposition of the compound in different solvents and in contact with the atmosphere. A similar boat conformation was found in five of six structures retrieved from the Cambridge Structural Database which contain (I) as a moiety. The present structure exhibits nearly the same packing motif as the recently found monoclinic polymorph.
引用
收藏
页码:226 / 228
页数:3
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