A triad [FeFe] hydrogenase system for light-driven hydrogen evolution

被引：51
|
作者：
Wang, Hong-Yan
Si, Gang
Cao, Wei-Ning
Wang, Wen-Guang
Li, Zhi-Jun
Wang, Feng
Tung, Chen-Ho
Wu, Li-Zhu [1 ]
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 29期
基金：
中国国家自然科学基金;
关键词：
ACTIVE-SITE; ELECTRON-TRANSFER; INTRAMOLECULAR ELECTRON; BIOMIMETIC MODEL; PORPHYRIN; LIGAND;
D O I：
10.1039/c1cc12200b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel molecular triad [FeFe]-H(2)ase 1, and its model complexes 2 and 3 have been successfully constructed. The multistep PET and long-lived Fe(I)Fe(0) species were found to be responsible for the better performance of triad 1 than that of 2 with 3 for light-driven H-2 evolution.
引用
收藏
页码：8406 / 8408
页数：3
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