Synthesis of amorphous CS2 by UV light irradiation

被引：1
|
作者：
Takahashi, Y
Kotake, S
Ohta, T
Matsumuro, A
Senoo, M
机构：
[1] NIPPON OIL & FATS CO LTD, TSUKUBA RES LAB, TSUKUBA, IBARAKI 30026, JAPAN
[2] NAGOYA UNIV, GRAD SCH, DEPT MICRO SYST ENGN, CHIKUSA KU, NAGOYA, AICHI 46401, JAPAN
来源：
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN | 1997年 / 105卷 / 03期
关键词：
carbon disulfide; ultraviolet light; photo-polymerization; amorphous; chemical bond;
D O I：
10.2109/jcersj.105.272
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Carbon disulfide liquid was irradiated by Hg lamp at room temperature. Solid phase was obtained by the photochemical reaction of ultraviolet light, which was analyzed by EPMA, TEM, FT-IR and XPS. (1) It was photo-polymerized compound of carbon and sulfur rather than a mere mixture of products of photolis. (2) It was nano-crystalline or almost amorphous. (3) The bonding manner was different from other CS2 solids prepared by high-pressure, plasma-polymerizing and anion catalyst techniques.
引用
收藏
页码：272 / 274
页数：3
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