Nickel(0)-Catalyzed N-Allylation of Amides and p-Toluenesulfonamide with Allylic Alcohols under Neat and Neutral Conditions

被引：29
|
作者：
Azizi, Mohamed Salah [1 ]
Edder, Youssef [2 ]
Karim, Abdallah [2 ]
Sauthier, Mathieu [1 ]
机构：
[1] Univ Artois, ENSCL, Cent Lille, Univ Lille,CNRS,UMR 8181,UCCS, F-59000 Lille, France
[2] Univ Cadi Ayyad, Equipe Chim Coordinat & Catalyse, Dept Chim, Fac Sci Semlalia, BP 2390, Marrakech, Morocco
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 2016卷 / 22期
关键词：
Homogeneous catalysis; Nickel; N-Allylation; Allylic alcohols; Amides; Electron-poor N atoms; CATALYZED HYDROALKOXYLATION REACTION; ONE-POT SYNTHESIS; ALLYLAMINE DERIVATIVES; CLAISEN REARRANGEMENT; 3-COMPONENT REACTION; DIRECT SUBSTITUTION; HYDROXY GROUP; COMPLEXES; PALLADIUM; NUCLEOPHILES;
D O I：
10.1002/ejoc.201600500
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Nickel(0)-catalyzed direct N-allylation of amides and p-toluenesulfonamide with allylic alcohols took place in the presence of Ni-0-diphosphine complexes. The corresponding N-allylated (and/or N, N-diallylated) products were obtained in moderate to high yields under neutral conditions.
引用
收藏
页码：3796 / 3803
页数：8
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