Synthesis and spectroscopic characterization of some novel Ru(II) and Ru(III) dimeric sulphoxide complexes containing the Schiff base N,N′-bis(2-chlorobenzylidene)-1,2-ethylenediamine as spacer

被引：1

作者：

Shukla, Satyendra N. ^{[1
]}

Gaur, Pratiksha ^{[1
]}

Prasad, Mahender ^{[2
]}

Kaur, Harpreet ^{[1
]}

Srivastava, Radhey S. ^{[3
]}

Agarwal, Kavita ^{[2
]}

机构：

[1] Govt Model Sci Coll, Coordinat Chem Res Lab, Dept Chem, Jabalpur 482001, Madhya Pradesh, India

[2] DMSRDE, Kanpur, Uttar Pradesh, India

[3] Univ Louisiana Lafayette, Lafayette, LA 70504 USA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 07期

关键词：

ruthenium; dimethylsulphoxide; tetramethylenesulphoxide; Schiff base;

D O I：

10.1080/00958970701502326

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the synthesis and characterization of anionic and neutral dimers of three general formulations viz. [{cis-RuCl2(SO)(3)}(2)(2-ClBENEN)]; [{trans-RuCl2(SO)(3)}(2)(2-ClBENEN)] and [image omitted][{RuCl4(SO)}(2)(2-ClBENEN)](2-); where SO = dimethylsulphoxide/tetramethylenesulphoxide; X = [(dmso)(2)H](+); Na+; [(tmso)H](+); and 2-ClBENEN = N,N'-bis(2-chlorobenzylidene)-1,2-ethylenediamine. These complexes were characterized on the basis of elemental analysis, magnetic susceptibility, electronic, FTIR, H-1-NMR and C-13{H-1}NMR spectroscopy. These complexes are rare examples where a Schiff-base ligand serves as a spacer group.

引用

页码：1137 / 1145

页数：9

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