Copper-catalyzed highly enantioselective synthesis of cyclic allylic and homoallylic alcohols with dialkylzinc reagents

被引：0

作者：

Pineschi, M ^{[1
]}

Del Moro, F ^{[1
]}

Crotti, P ^{[1
]}

Di Bussolo, V ^{[1
]}

Macchia, F ^{[1
]}

机构：

[1] Univ Pisa, Dipartimento Chim Bioorgan & Biofarm, I-56126 Pisa, Italy

来源：

SYNTHESIS-STUTTGART | 2005年 / 02期

关键词：

asymmetric catalysis; organozinc reagents; copper; kinetic resolution; desymmetrization;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The copper-phosphoramidite catalyzed addition of dialkylzinc reagents to racemic or meso allylic epoxides can be synthetically exploited in different ways, depending on the substrates and reaction conditions used.

引用

页码：334 / 337

页数：4

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