The Kabachnik-Fields Reaction in the Synthesis of Polyaminophosphonate Derivatives of p-tert-Butylthiacalix[4]arene

被引:0
|
作者
Shibaeva, K. S. [1 ]
Mostovaya, O. A. [1 ]
Nazarova, A. A. [1 ]
Shurpik, D. N. [1 ]
Shiabiev, I. E. [1 ]
Kuznetsova, D. I. [1 ]
Stoykov, I. I. [1 ]
机构
[1] Kazan Fed Univ, Butlerov Chem Inst, Ul Kremlevskaya 18, Kazan 420008, Tatarstan, Russia
基金
俄罗斯基础研究基金会;
关键词
Kabachnik-Fields reaction; thiacalix[4]arene; aminophosphonate; AMINO-ACIDS; AMINOPHOSPHONIC ACIDS; MOLECULAR RECOGNITION; FUNCTIONALIZATION; COMPLEXATION; AMIDE;
D O I
10.1134/S1070363218090086
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel derivatives of p-tert-butylthiacalix[4]arene containing four or eight 1-aminophosphonate groups at the lower rim of the macrocycle in 1,3-alternate conformation have been synthesized via the Kabachnik-Fields reaction. These compounds are promising synthetic receptors for biologically important acids. It has been shown that complete phosphorylation of the first generation dendrimer containing eight primary amino groups is impeded in the case of cyclic ketones.
引用
收藏
页码:1812 / 1817
页数:6
相关论文
共 50 条
  • [41] Synthesis of hydrophospohoryl derivatives of the antifungal antibiotic pimaricin by the Kabachnik-Fields reaction
    Belakhov, V. V.
    Shenin, Yu. D.
    Ionin, B. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2008, 78 (02) : 305 - 312
  • [42] Synthesis of α-Aminophosphonates and Related Derivatives; The Last Decade of the Kabachnik-Fields Reaction
    Varga, Petra R.
    Keglevich, Gyorgy
    MOLECULES, 2021, 26 (09):
  • [43] Synthesis and crystal structure of p-tert-butylthiacalix[8]arene:: A new member of thiacalixarenes
    Kondo, Y
    Endo, K
    Iki, N
    Miyano, S
    Hamada, F
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2005, 52 (1-2) : 45 - 49
  • [44] Inconvertible p-tert-butylthiacalix[4]arene-core-star polystyrene conformers
    Jung, Ji-Hye
    Oh, Joongsuk
    Lim, Yeong-Gweon
    Chang, Taihyun
    Paik, Hyun-jong
    RSC ADVANCES, 2016, 6 (78): : 74614 - 74619
  • [45] A hexacoordinated P-bridged calixarene derivative -: Phosphorylation of p-tert-butylthiacalix[4]arene
    Gloede, J
    Ozegowski, S
    Weber, D
    Habicher, WD
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2003, 178 (04) : 923 - 927
  • [46] Lactic acid copolyesters with carboxyl derivatives of p-tert-butylthiacalix[4]arene: synthesis and effect of macrocycle conformation on the physicochemical properties
    A. A. Vavilova
    V. V. Gorbachuk
    D. N. Shurpik
    P. L. Padnya
    A. V. Gerasimov
    O. A. Mostovaya
    I. I. Stoikov
    Russian Chemical Bulletin, 2019, 68 : 2098 - 2104
  • [47] Ethylene polymerization promoted by dinuclear titanium p-tert-butylthiacalix[4]arene complexes
    Proto, Antonio
    Giugliano, Francesca
    Capacchione, Carmine
    EUROPEAN POLYMER JOURNAL, 2009, 45 (07) : 2138 - 2141
  • [48] Synthesis of α-Aminophosphonate Derivatives by Microwave-Assisted Kabachnik-Fields Reaction
    Balint, Erika
    Fazekas, Eszter
    Tripolszky, Anna
    Kangyal, Reka
    Milen, Matyas
    Keglevich, Gyoergy
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2015, 190 (5-6) : 655 - 659
  • [49] Crystal structure and inclusion property of p-tert-butylthiacalix [6]arene
    Iki, N
    Morohashi, N
    Suzuki, T
    Ogawa, S
    Aono, M
    Kabuto, C
    Kumagai, H
    Takeya, H
    Miyanari, S
    Miyano, S
    TETRAHEDRON LETTERS, 2000, 41 (15) : 2587 - 2590
  • [50] Synthesis of Aminobismethylenephosphonic Acids on a Platform of p-tert-Butylthiacalix[4]arene in 1,3-alternate Configuration
    Shibaeva, K. S.
    Nazarova, A. A.
    Kuznetsova, D. I.
    Stoikov, I. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2016, 86 (03) : 579 - 583