Structural and Operational Optimality of Adsorptive Reactors

被引:5
|
作者
Hussainy, Mamoon [1 ]
Agar, David W. [1 ]
机构
[1] TU Dortmund, Fak Bio & Chem Ingn Wesen, Lehrstuhl Chem Verfahrenstech, Emil Figge Str 66, D-44227 Dortmund, Germany
关键词
Adsorptive reactors; Claus reaction; Deacon reaction; Macrostructuring; Temperature profiling; FLUID DISPERSION COEFFICIENTS; ENHANCED REACTION PROCESS; PACKED-BEDS; FUNCTIONALITIES; SIMULATION; ADSORBENT; CATALYST; HYDROGEN; NUMBERS; LEVEL;
D O I
10.1002/ceat.201600197
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Adsorptive reactors represent a promising genre of multifunctional reactors combining the highly compatible adsorptive and reactive functionalities. Although they offer multiple benefits to the overall process flowsheet, overcoming the low space time yields, which are an inherent drawback of their cyclic operation, and unwanted functionality interference remain a challenge. The potential of temperature profiling to expedite the macrostructuring of adsorptive reactors for performance optimization is presented. Two industrially relevant reactions have been investigated as test cases: the Claus reaction for recovering sulfur from acid gas and the Deacon reaction for the plant-internal recycling of chlorine via HCl oxidation.
引用
收藏
页码:2135 / 2141
页数:7
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