Zeolite-supported Ni catalyst for methane reforming with carbon dioxide

被引：22

作者：

Frontera, P. ^{[1
]}

Aloise, A. ^{[2
]}

Macario, A. ^{[2
]}

Crea, F. ^{[2
]}

Antonucci, P. L. ^{[1
]}

Giordano, G. ^{[2
]}

Nagy, J. B. ^{[1
]}

机构：

[1] Mediterranea Univ Reggio Calabria, Dept Mat & Mech, I-89100 Reggio Di Calabria, Italy

[2] Univ Calabria, Dept Chem Engn & Mat, I-87036 Arcavacata Di Rende, Italy

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2011年 / 37卷 / 2-5期

关键词：

CO(2)/CH(4) reforming; Nickel catalyst; Silicalite-1; Coke formation; SYNTHESIS GAS; CO2; SYNGAS;

D O I：

10.1007/s11164-011-0249-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the present work, we compare the catalytic behaviour, in the dry reforming of methane, of Ni-based Silicalite-1 type catalyst obtained by different post-synthesis treatments. The Silicalite-1 typematerial, used as Ni-support, has been treated in order to observe the role of the silanol groups on the Ni impregnation, and then on the overall catalyst performance. Among the applied treatments (ionic-exchange, calcinations and silylation), the silylation is the one that allows the formation of smaller and more reducible Ni-oxide species that not only improve the methane conversion but also reduce the deactivation of the catalyst, due to the coke deposition.

引用

页码：267 / 279

页数：13

共 50 条

[1] Zeolite-supported Ni catalyst for methane reforming with carbon dioxide
P. Frontera
A. Aloise
A. Macario
F. Crea
P. L. Antonucci
G. Giordano
J. B. Nagy
[J]. Research on Chemical Intermediates, 2011, 37 : 267 - 279
[2] Activity of different zeolite-supported Ni catalysts for methane reforming with carbon dioxide
Luengnaruemitchai, Apanee
Kaengsilalai, Athiya
[J]. CHEMICAL ENGINEERING JOURNAL, 2008, 144 (01) : 96 - 102
[3] CATALYTIC REFORMING OF METHANE WITH CARBON-DIOXIDE OVER PENTASIL ZEOLITE-SUPPORTED NICKEL-CATALYST
CHANG, JS
PARK, SE
LEE, KW
CHOI, MJ
[J]. ZEOLITES AND RELATED MICROPOROUS MATERIALS: STATE OF THE ART 1994, 1994, 84 : 1587 - 1594
[4] Stabilities of zeolite-supported Ni catalysts for dry reforming of methane
Fakeeha, Anis H.
Khan, Wasim U.
Al-Fatesh, Ahmed S.
Abasaeed, Ahmed E.
[J]. CHINESE JOURNAL OF CATALYSIS, 2013, 34 (04) : 764 - 768
[5] Effect of MgO loading over zeolite-supported Ni catalysts in methane reforming with carbon dioxide for synthesis gas production
Aline Simoura de Jesus
Maikel L. Maloncy
Marcelo S. Batista
[J]. Reaction Kinetics, Mechanisms and Catalysis, 2017, 122 : 501 - 511
[6] Effect of MgO loading over zeolite-supported Ni catalysts in methane reforming with carbon dioxide for synthesis gas production
de Jesus, Aline Simoura
Maloncy, Maikel L.
Batista, Marcelo S.
[J]. REACTION KINETICS MECHANISMS AND CATALYSIS, 2017, 122 (01) : 501 - 511
[7] Catalytic activity and coke resistance in the carbon dioxide reforming of methane to synthesis gas over zeolite-supported Ni catalysts
Chang, JS
Park, SE
Chon, HZ
[J]. APPLIED CATALYSIS A-GENERAL, 1996, 145 (1-2) : 111 - 124
[8] Potential of Ni supported on KH zeolite catalysts for carbon dioxide reforming of methane
Kaengsilalai, Athiya
Luengnaruemitchai, Apanee
Jitkarnka, Sirirat
Wongkasemjit, Sujitra
[J]. JOURNAL OF POWER SOURCES, 2007, 165 (01) : 347 - 352
[9] Effect of Manganese and zeolite composition on zeolite-supported Ni-catalysts for dry reforming of methane
Najfach, Aaron J.
Almquist, Catherine B.
Edelmann, Richard E.
[J]. CATALYSIS TODAY, 2021, 369 : 31 - 47
[10] Ni/Y- Zeolite Catalysts for Carbon Dioxide Reforming of Methane
Fakeeha, A. H.
Al-Fatesh, A. S.
Abasaeed, A. E.
[J]. ADVANCES IN CHEMICAL ENGINEERING II, PTS 1-4, 2012, 550-553 : 325 - 328

← 1 2 3 4 5 →