1,2-amino alcohols by photocycloaddition ring opening sequences

被引：0

作者：

Schroder, J ^{[1
]}

Bach, T ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

JOURNAL OF INFORMATION RECORDING | 1998年 / 24卷 / 3-4期

关键词：

1,2-amino alcohols; oxetanes; photochemistry; natural products;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The Paterno-Buchi reaction of aldehydes and N-acyl enamines generate cis-3-aminooxetanes with high regio- and satisfactory diastereoselectivities (d.r.9/1). Different ring opening reaction opens routes to syn- and anti-1, 2-amino alcohols like pseudoephedrine (10) and ephedrine (13). Another natural product containing a cis-3-aminooxetane structure is oxetin (14), an antibiotic beta-amino acid. It was prepared by photocycloaddition and removal of protecting groups.

引用

页码：285 / 288

页数：4

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