Synthesis and reactions of 2-azido-1,3-di(benzyloxy)imidazolium hexafluoridophosphate

被引：5
|
作者：
Laus, Gerhard [1 ]
Kostner, Mirco E. [1 ]
Kahlenberg, Volker [2 ]
Schottenberger, Herwig [1 ]
机构：
[1] Univ Innsbruck, Fac Chem & Pharm, A-6020 Innsbruck, Austria
[2] Univ Innsbruck, Inst Mineral & Petrog, A-6020 Innsbruck, Austria
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2016年 / 71卷 / 09期
关键词：
azide; aziridine; imidazole; phosphazene; phosphazide; CRYSTAL-STRUCTURE; BENZENESULFONYL AZIDE; STAUDINGER REACTION; IONIC LIQUIDS; CYCLOADDITION; SALTS; PHOSPHAZIDE; DERIVATIVES;
D O I：
10.1515/znb-2016-0104
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
2-Azido-1,3-di(benzyloxy) imidazolium hexa-fluoridophosphate was obtained from the corresponding 2-bromo compound by reaction with sodium azide. Cycloaddition of the 2-azido compound with norbornene and norbornadiene gave the respective tricyclic aziridine and bicyclic azaoctadiene. Addition of triphenylphosphane yielded the phosphazide which upon heating eliminated dinitrogen to afford the phosphazene. The crystal structures of five compounds were determined by X-ray diffraction.
引用
收藏
页码：997 / 1003
页数：7
相关论文
共 50 条
  • [41] Heterogeneously Catalyzed Diastereoselective Synthesis of 2-Nitro-1,3-di(pyridin-2-yl)propane-1,3-diols
    Schulz, Martin
    Wimmer, Katja
    Goerls, Helmar
    Westerhausen, Matthias
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2011, 66 (06): : 611 - 623
  • [42] A reagent for safe and efficient diazo-transfer to primary amines: 2-azido-1,3-dimethylimidazolinium hexafluorophosphate
    Kitamura, Mitsuru
    Kato, So
    Yano, Masakazu
    Tashiro, Norifumi
    Shiratake, Yuichiro
    Sando, Mitsuyoshi
    Okauchi, Tatsuo
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2014, 12 (25) : 4397 - 4406
  • [43] SYNTHESIS AND POLYMERIZATION OF THE 4 1,3-DI(CYANO AND-OR CARBOMETHOXY)-SUBSTITUTED BUTADIENES
    AHN, KD
    HALL, HK
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1981, 19 (03) : 629 - 644
  • [44] Synthesis and properties of polyimides from 1,3-di(p-dimethylaminobenzyl)-imidazolidine-2-thion
    Seckin, T
    Çetinkaya, E
    Köytepe, S
    Yigit, B
    POLYMER BULLETIN, 2003, 50 (03) : 139 - 146
  • [45] 1,3-DI(TERT-BUTYL)-2,4-DICHLORODIAZADIPHOSPHETIDINE
    SCHERER, OJ
    KLUSMANN, P
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1969, 8 (10) : 752 - &
  • [46] SYNTHESIS OF CROWN-ESTERS BASED ON 1,3-DICARBOXYADAMANTANES AND 1,3-DI(CARBOXYMETHYL)ADAMANTANES
    YURCHENKO, AG
    LIKHOTVORIK, IR
    MELNIK, NN
    ZHURNAL ORGANICHESKOI KHIMII, 1990, 26 (08): : 1808 - 1809
  • [47] 1,3-DI(2-THIENYL)PROPEN-1-ONE
    ZHENGDONG, L
    GENBO, S
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1995, 51 : 681 - 683
  • [48] 1,3-DI(TERT-BUTYL)-2,4-DICHLORODIAZAPHOSPHAARSETIDINE
    SCHERER, OJ
    SCHNABL, G
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1976, 31 (01): : 142 - 143
  • [49] Synthetic methods for preparing 1,3-di(2-pyridyl)azulene
    Oda, Mitsunori
    Kishi, Sayaka
    Thanh, Nguyen Chung
    Kuroda, Shigeyasu
    HETEROCYCLES, 2007, 71 (06) : 1413 - +
  • [50] THE VIBRATIONAL-SPECTRA, MOLECULAR-STRUCTURE AND CONFORMATION OF ORGANIC AZIDES .2. 2-AZIDO-1,3-BUTADIENE
    SCHEI, SH
    PRIEBE, H
    NIELSEN, CJ
    KLAEBOE, P
    JOURNAL OF MOLECULAR STRUCTURE, 1986, 147 (3-4) : 203 - 215
12345