Densities and Viscosities for the Ternary System of 1,2,3,4-Tetrahydronaphthalene plus Isopropylcyclohexane plus Cyclopropanemethanol and Corresponding Binaries at T = (293.15 to 343.15) K

被引:8
|
作者
Liu, Zhaoshan [1 ]
Cai, Mengsha [1 ]
Xu, Sanshu [2 ]
Guo, Yongsheng [1 ]
Fang, Wenjun [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310058, Zhejiang, Peoples R China
[2] AVIC, Nanjing Engn Inst Aircraft Syst, Nanjing 210000, Jiangsu, Peoples R China
来源
基金
中国国家自然科学基金;
关键词
REFRACTIVE-INDEXES; EXCESS VOLUMES; SOUND VELOCITIES; SURFACE-TENSION; BULK MODULUS; N-HEXADECANE; FLASH-POINT; MIXTURES; ETHANOL; LIQUIDS;
D O I
10.1021/acs.jced.8b00662
中图分类号
O414.1 [热力学];
学科分类号
摘要
Measurements on density and viscosity at atmospheric pressure for the ternary system 1,2,3,4-tetrahydronaphthalene (1) + isopropylcyclohexane (2) + cyclopropanemethanol (3) and three corresponding binary systems from (293.15 to 343.15) K have been carried out over the whole composition range. The excess molar volumes (V-m(E)) and viscosity deviations (Delta eta) of the ternary system have been derived from the experimental data and then fitted to the Cibulka, Singh, Redlich-Kister, and Nagata-Tamura equations, respectively. The binary subsystems were correlated by Redlich-Kister equation. For the system of 1,2,3,4-tetrahydronaphthalene + isopropylcyclohexane, the curve of the V-m(E) reveals a wing shape. The V-m(E) values are positive for the other two binary systems of 1,2,3,4-tetrahydronaphthalene + cyclopropanemethanol and isopropylcyclohexane + cyclopropanemethanol. While the value of Delta eta for all three binary systems is negative over the entire composition range. The results are interpreted with molecular interactions and structural effects.
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页码:4596 / 4605
页数:10
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