Preliminary analysis of the H-1- and C-13-NMR spectra of poly(3-vinyl-1-methylindole)

被引：0
|
作者：
Trumbo, DL
机构：
[1] S. C. Johnson Polymer, S. C. Johnson and Son, Inc., Racine, WI 53403-2236
来源：
POLYMER BULLETIN | 1996年 / 37卷 / 01期
关键词：
D O I：
10.1007/BF00313821
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The title monomer was synthesized and polymerized via free radical initation. The high field H-1- and C-13-NMR spectra were recorded and analyzed. Many resonances displayed multiplicities indicating a sensitivity to polymer stereochemistry but, in most cases, the resolution was insufficient for any reasonable interpretations to be made. The resonances that were well enough resolved for relatively accurate measurements to be made were analyzed in terms of polymer stereochemistry. The analysis suggests that poly(3-vinyl-1-methyl-indole) is an atactic polymer.
引用
收藏
页码：75 / 80
页数：6
相关论文
共 50 条
  • [21] H-1-NMR AND C-13-NMR SPECTRA OF FENOBAM
    PELLIZER, G
    RUBESSA, F
    JOURNAL OF PHARMACEUTICAL SCIENCES, 1983, 72 (02) : 189 - 190
  • [22] SIMULATION OF C-13-NMR AND H-1-NMR SPECTRA
    ZUPAN, J
    LAHTUSAR, L
    TUSAR, M
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 202 : 2 - COMP
  • [23] A H-1- and C-13-NMR study of seven ajmaline-type alkaloids
    Jokela, R
    Lounasmaa, M
    PLANTA MEDICA, 1996, 62 (06) : 577 - 579
  • [24] Analysis of the 1H- and 13C-NMR spectra of poly(5-vinyl-3-benzodioxole)
    Polym Bull (Berlin), 1 (67):
  • [25] H-1-NMR AND C-13-NMR SPECTRA OF THIOCOLCHICINE AND DERIVATIVES - A COMPLETE ANALYSIS
    CLERICI, F
    MOTTADELLI, S
    ROSSI, LM
    JOURNAL OF NATURAL PRODUCTS-LLOYDIA, 1995, 58 (02): : 259 - 263
  • [26] H-1-NMR AND C-13-NMR SPECTRA OF ASCORBATE AND ISOASCORBATE
    LOHMANN, W
    BEINHAUER, K
    SAPPER, H
    NATURWISSENSCHAFTEN, 1984, 71 (09) : 477 - 478
  • [27] A study of the mechanism of the oxidative thermal degradation of poly(ethylene oxide) and poly(propylene oxide) using H-1- and C-13-NMR
    Yang, L
    Heatley, F
    Blease, TG
    Thompson, RIG
    EUROPEAN POLYMER JOURNAL, 1996, 32 (05) : 535 - 547
  • [28] H-1- and C-13-NMR spectral data of five sarpagine-type alkaloids
    Jokela, R
    Lounasmaa, M
    HETEROCYCLES, 1996, 43 (05) : 1015 - 1020
  • [29] H-1-AND C-13-NMR SPECTRA OF CAMPTOTHECIN AND DERIVATIVES
    EZELL, EL
    SMITH, LL
    JOURNAL OF NATURAL PRODUCTS, 1991, 54 (06): : 1645 - 1650
  • [30] H-1-NMR AND C-13-NMR SPECTRA OF 3-ARYL-2-AZAINDOLIZINES
    ASHAUER, U
    WOLFF, C
    HALLER, R
    ARCHIV DER PHARMAZIE, 1986, 319 (01) : 43 - 52
12345