Macrocyclic and acyclic bis(2,5-diphenyl-1,3,4-oxadiazole)s with electron-transporting and hole-blocking ability in organic electroluminescent devices

被引：11

作者：

Ono, K ^{[1
]}

Ezaka, S

Higashibata, A

Hosokawa, R

Ohkita, M

Saito, K

Suto, M

Tomura, M

Matsushita, Y

Naka, S

Okada, H

Onnagawa, H

机构：

[1] Nagoya Inst Technol, Dept Life & Mat Engn, Showa Ku, Nagoya, Aichi 4668555, Japan

[2] Dow Corning Asia Ltd, Chigusa Ku, Ichihara 2990108, Japan

[3] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

[4] Toyama Univ, Fac Engn, Dept Elect & Elect Engn, Gofu Ku, Toyama 9308555, Japan

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2005年 / 206卷 / 15期

关键词：

charge transport; electroluminescence; macrocycles; 1,3,4-oxadiazole; structure-property relations;

D O I：

10.1002/macp.200500122

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two types of bis(2,5-diphenyl-1,3,4-oxadiazole)s, macrocyclic and acyclic, were prepared and evaluated as electron-transporting and hole-blocking materials in phosphorescent EL devices. Maximum efficiencies of eta(ext)=10.4% at J=0.11 mA.cm(-1) for the macrocycle and eta(ext)=14.1% at J=3.01 mA.cm(-1) for the acycle were observed. X-ray crystallographic analysis and DSC measurements revealed a strong intermolecular interaction between the macrocylces and weaker intermolecular interactions between the acycles. The EL characteristics depend on the intermolecular interactions.

引用

页码：1576 / 1582

页数：7

共 50 条

[21] Surface plasmon-coupled ultraviolet emission of 2,5-diphenyl-1,3,4-oxadiazole
Malicka, J
Gryczynski, I
Gryczynski, Z
Lakowicz, JR
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (50): : 19114 - 19118
[22] Synthesis of a novel β-diketone containing carbazole and 2,5-diphenyl-1,3,4-oxadiazole fragments
Huaijun Tang
Zhiguo Zhang
Changjie Cong
Keli Zhang
Russian Journal of Organic Chemistry, 2009, 45 : 559 - 563
[23] Bipyridyl substituted triazoles as hole-blocking and electron-transporting materials for organic light-emitting devices
Ichikawa, Musubu
Fujimoto, Soichi
Miyazawa, Yuta
Koyama, Toshiki
Yokoyama, Norimasa
Miki, Tetsuzo
Taniguchi, Yoshio
ORGANIC ELECTRONICS, 2008, 9 (01) : 77 - 84
[24] PHOTOPHYSICS OF ARYL SUBSTITUTED 1,3,4-OXADIAZOLES - THE TRIPLET-STATE OF 2,5-DIPHENYL-1,3,4-OXADIAZOLE
RULLIERE, C
ROBERGE, PC
CHEMICAL PHYSICS LETTERS, 1983, 97 (02) : 247 - 252
[25] QUANTUM-CHEMICAL INVESTIGATION OF ELECTRON STRUCTURES AND SPECTRO-LUMINESCENCE CHARACTERISTICS OF 2,5-DIPHENYL-1,3,4-OXADIAZOLE MOLECULES
GODIK, VA
SHABLYGIN, MV
RODIONOV, AN
SIMONOV, AP
SHIGORIN, DN
ZHURNAL FIZICHESKOI KHIMII, 1985, 59 (03): : 651 - 655
[26] Structural optimization of 2,5-diarylsiloles as excellent electron-transporting materials for organic electroluminescent devices
Uchida, M
Izumizawa, T
Nakano, T
Yamaguchi, S
Tamao, K
Furukawa, K
CHEMISTRY OF MATERIALS, 2001, 13 (08) : 2680 - 2683
[27] Photoluminescent and electrochemical properties of novel poly(aryl ether)s with isolated hole-transporting carbazole and electron-transporting 1,3,4-oxadiazole fluorophores
Hwang, SW
Chen, Y
MACROMOLECULES, 2002, 35 (14) : 5438 - 5443
[28] PHOTOCHEMISTRY OF HETEROCYCLIC-COMPOUNDS .4. PHOTOCHEMICAL REACTION OF 2,5-DIPHENYL-1,3,4-OXADIAZOLE WITH INDAZOLES
OE, K
TASHIRO, M
TSUGE, O
CHEMISTRY LETTERS, 1976, (02) : 153 - 156
[29] Electronic structure of ordered Langmuir-Blodgett films of an amphiphilic derivative of 2,5-diphenyl-1,3,4-oxadiazole
Casu, MB
Imperia, P
Schrader, S
Schulz, B
Fangmeyer, F
Schürmann, H
NOVEL METHODS TO STUDY INTERFACIAL LAYERS, 2001, 11 : 121 - 135
[30] Cobalt(II) nitrate promoted cyclization of benzoyl hydrazone for the synthesis of 2,5-diphenyl-1,3,4-oxadiazole derivatives
Li, Xiaojun
Liao, Shangtie
Chen, Yu
Xia, Chengcai
Wang, Guodong
JOURNAL OF CHEMICAL RESEARCH, 2021, 45 (11-12) : 1038 - 1041

← 1 2 3 4 5 →