The allenic derivatives of biologically active natural sesquiterpenes were synthesized by two reaction sequence: addition of Seyferth reagent producing dibromocyclopropanes then the allenic derivative formation by Hiyama reaction. The structure of all products was determined using H-1 and C-13 NMR.
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Univ Aix Marseille 3, Fac Sci & Tech St Jerome, ESA CNRS 6009, F-13397 Marseille 20, FranceUniv Aix Marseille 3, Fac Sci & Tech St Jerome, ESA CNRS 6009, F-13397 Marseille 20, France
Chatel, F
Faure, R
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Univ Aix Marseille 3, Fac Sci & Tech St Jerome, ESA CNRS 6009, F-13397 Marseille 20, FranceUniv Aix Marseille 3, Fac Sci & Tech St Jerome, ESA CNRS 6009, F-13397 Marseille 20, France
Faure, R
Boyer, G
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Univ Aix Marseille 3, Fac Sci & Tech St Jerome, ESA CNRS 6009, F-13397 Marseille 20, FranceUniv Aix Marseille 3, Fac Sci & Tech St Jerome, ESA CNRS 6009, F-13397 Marseille 20, France
Boyer, G
Galy, JP
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Univ Aix Marseille 3, Fac Sci & Tech St Jerome, ESA CNRS 6009, F-13397 Marseille 20, FranceUniv Aix Marseille 3, Fac Sci & Tech St Jerome, ESA CNRS 6009, F-13397 Marseille 20, France