Catalyst-free photo-reductions of aromatic olefins and carbonyl compounds

被引：3

作者：

Wu, Jieliang ^{[1
]}

Yan, Boyu ^{[1
]}

Meng, Jiangtao ^{[1
]}

Yang, Enqin ^{[1
]}

Ye, Xiushen ^{[2
]}

Yao, Qiuli ^{[1
,2
]}

机构：

[1] Zunyi Med Univ, Gener Drug Res Ctr Guizhou Prov, Dept Pharm, Key Lab Biocatalysis & Chiral Drug Synth Guizhou, 6 Xuefu Rd West, Zunyi 563000, Guizhou, Peoples R China

[2] Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2022年 / 20卷 / 44期

基金：

中国国家自然科学基金;

关键词：

COMBINING PHOTOCATALYSIS; ASYMMETRIC HYDROGENATION; KETONES; OXIDE;

D O I：

10.1039/d2ob01353c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We describe herein a catalyst-free, traditional reductant-free strategy for the direct photoinduced hydrogenation or deuteration of aromatic olefins, ketones, and aldehydes with simple bases as the only additives. A broad range of substrates were demonstrated with high yields and deuterium incorporations. Mechanistic experiments indicate a radical mechanism.

引用

页码：8638 / 8642

页数：6

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