Facile Synthesis of Several Oleanane-Type Triterpenoid Saponins

被引：16

作者：

Liu, Qingchao ^{[1
]}

Fan, Zheng ^{[1
]}

Li, Dong ^{[1
]}

Li, Wenhong ^{[1
]}

Guo, Tiantian ^{[2
]}

机构：

[1] NW Univ Xian, Dept Pharmaceut Engn, Xian 710069, Shaanxi, Peoples R China

[2] Yanan Univ, Xian Innovat Coll, Dept Med, Xian 710100, Shaanxi, Peoples R China

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 2010年 / 29卷 / 8-9期

关键词：

Oleanane-type triterpenoid saponin; Glucuronide residue; TEMPO-mediated oxidation;

D O I：

10.1080/07328303.2011.555898

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Facile synthesis of the natural oleanane-type triterpenoid saponin 1 isolated from Panax japonicus C. A. Meyer var major (Burk.) C. Y. Wu et K. M. Feng and its derivatives is reported. The glucuronide residue in saponins at a later stage via TEMPO-mediated oxidation of the primary-OH has been achieved. All structures of new compounds were established by means of H-1 NMR, C-13 NMR, HRMS, and optical rotation.

引用

页码：386 / 402

页数：17

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