Silica hybrid particles with nanometre polymer shells and their influence on the toughening of polypropylene

Colloidal silica particles were synthesized by the sol-gel process and then modified with 3-methacryloxypropyltrimethoxysilane (gamma-MPS) to induce vinyl groups on the surface of the silica particles. By means of in situ emulsion copolymerization of methyl methacrylate (MMA) and butyl acrylate (BA), a series of core-shell silica hybrid particles with nanometre poly(MMA-co-BA) shells were fabricated, which were subsequently compounded with isotactic polypropylene (PP) in the molten state. Upon increasing the feed silica : monomer ratio from 1 : 1 to 4 : 1, the poly(MMA-co-BA) shell thickness on the silica core decreased from 50 nm to 10 nm. Owing to the existence of the nanometre poly(MMA-co-BA) shells, the silica hybrid particles were monodispersed in the PP matrix, causing homogeneous debonding at the PP/silica interface, followed by plastic void expansion and matrix shear yielding during impact fracture. These deformation mechanisms greatly toughened the PP-silica composites. A critical shell thickness of poly(MMA-co-BA) was needed to achieve optimal mechanical properties. That is, when the polymer shell thickness was 15 nm, compared to pure PP, the impact toughness of the PP-silica composite was more than doubled with little degradation of tensile strength.