The determination of the integral enthalpies of mixing of liquid Au-In-Sn alloys and the enthalpy of formation of the Au4In3Sn3 compound

被引：2

作者：

Watson, A. ^{[1
]}

Borzone, G. ^{[2
]}

Parodi, N. ^{[2
]}

Cacciamani, G. ^{[2
]}

机构：

[1] Univ Leeds, Inst Mat Res, Sch Proc Environm & Mat Engn, Leeds, W Yorkshire, England

[2] Univ Genoa, Dept Chem & Ind Chem, I-16146 Genoa, Italy

来源：

THERMOCHIMICA ACTA | 2010年 / 510卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

High temperature calorimetry; Alloy thermochemistry; Enthalpy of formation; Enthalpy of mixing; Lead-free solders;

D O I：

10.1016/j.tca.2010.06.018

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

With a view to modelling the Au-In-Sn alloy system, the enthalpies of mixing of liquid Au-In-Sn alloys have been measured as a function of Au content by drop calorimetry at 609 degrees C for constant In:Sn ratios of 1:1, 1:3 and 3:1. For each of the three sections studied, the enthalpies of mixing were exothermic. In addition, the enthalpy of formation of the ternary Au4In3Sn3 at 298 K was measured both by direct-reaction calorimetry and by tin-solution calorimetry. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：24 / 31

页数：8

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