Synthesis and structural characterization of terminal (diisopropylamino)borylene complexes of group 8 metals

被引：4

作者：

Vidovic, Dragoslav ^{[1
]}

Pierce, Glesni A. ^{[1
]}

Coombs, Natalie D. ^{[1
]}

Kays, Deborah L. ^{[2
]}

Thompson, Amber L. ^{[1
]}

Stasch, Andreas ^{[3
]}

Aldridge, Simon ^{[1
]}

机构：

[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

[2] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[3] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

MAIN GROUP CHEMISTRY | 2010年 / 9卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

Boron; borylene; boryl; iron; ruthenium; halide abstraction; COORDINATION CHEMISTRY; HALIDE ABSTRACTION; REACTIVITY; ANALOG; BORON; CO;

D O I：

10.3233/MGC-2010-0005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses and first structural characterization of terminal (diisopropylamino)borylene complexes are reported. The B-11 NMR chemical shifts for these novel systems (delta(B) 93.8 and 90.2 for [Cp'Fe(CO)(2)((BNPr2)-Pr-i)][BAr4f], 3, and [CpRu(CO)(2)((BNPr2)-Pr-i)][BAr4f], 4, respectively) are ca. 40 ppm downfield of those measured for the boryl precursor complexes, consistent with observations for related trimethylsilyl and cyclohexylamino substituted compounds. Structurally, the linearity of the M - B - N fragment in each case and the marked shortening of the M - B bonds (cf. the single bonds found in boryl complexes CpFe(CO)(2)((BNPr2)-Pr-i)Cl, 1b, and CpRu(CO)(2)((BNPr2)-Pr-i)Cl, 2) reflect the fact that the M - B bond order in borylene systems 3 and 4 is between one and two.

引用

页码：57 / 65

页数：9

共 50 条

[41] Synthesis and structural characterization of group 6 transition metal complexes with terminal fluoromethylidyne (CF) ligands; a DFT/NBO/NRT comparison of bonding characteristics of terminal NO, CF and CH ligands
Huang, Hui
Hughes, Russell P.
Rheingold, Arnold L.
DALTON TRANSACTIONS, 2011, 40 (01) : 47 - 55
[42] Structural, acidity and chemical properties of some dihydrogen/hydride complexes of Group 8 metals with cyclopentadienyls and related ligands
Jia, GC
Lau, CP
COORDINATION CHEMISTRY REVIEWS, 1999, 190 : 83 - 108
[43] Synthesis and reactivity of new terminal carbido complexes of the late transition metals
Johnson, Marc J. A.
Stewart, Michael H.
Kampf, Jeff W.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
[44] Synthesis and Characterization of Schiff Bases Complexes of Divalent Metals
Singh, R. P.
Gupta, D.
ASIAN JOURNAL OF CHEMISTRY, 2010, 22 (02) : 1073 - 1078
[45] Synthesis and Characterization of Complexes of Some Transition Metals with Benzoyldithiocarbazate
Yang, X.
Xu, P.
Liu, J.
Tan, M.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 27 (07):
[46] Synthesis and characterization of complexes of some transition metals with benzoyldithiocarbazate
Yang, XP
Xu, PF
Liu, JH
Tan, MY
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1997, 27 (07): : 1039 - 1046
[47] Synthesis and characterization of some transition metals polymer complexes
Masoud, Mamdouh S.
Abdou, Azza E. H.
Ahmed, Wael M.
JOURNAL OF MOLECULAR STRUCTURE, 2015, 1095 : 135 - 143
[48] A Review: Synthesis and characterization of metals complexes with paracetamol drug
AL-Ayash, Salam R.
AL-Noor, Taghreed H.
ANALYTICAL SCIENCE AND TECHNOLOGY, 2022, 35 (04): : 143 - 152
[49] Synthesis and characterization of pyrazole complexes of divalent metals.
Grotjahn, DB
Combs, D
Van, S
Schneider, C
Rideout, M
Concolino, T
Incarvito, C
Lam, M
Rheingold, AL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U806 - U806
[50] Synthesis and structures of N-bis(diisopropylamino)phosphanyl-substituted aminocarbene complexes of the metals chromium, molybdenum and tungsten
Streubel, R
Hobbold, M
Jeske, J
Ruthe, F
Jones, PG
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 529 (1-2) : 351 - 356

← 1 2 3 4 5 →