Enantioselective additions of diphenylzinc to aldehydes using chiral pyrrolidinylmethanol derivatives as catalysts

被引：68
|
作者：
Zhao, G
Li, XG
Wang, XR
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
[2] Anhui Normal Univ, Inst Organ Chem, Anhua, Peoples R China
来源：
TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 03期
关键词：
D O I：
10.1016/S0957-4166(01)00074-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The enantioselective addition of diphenylzinc to aldehydes using a series of chiral ligands derived from (S)-proline afforded secondary alcohols in high yields and with high enantiomeric excesses of up to 92.6%. The configuration of the secondary alcohol enantiomer obtained was found to be dependent on the catalyst used. (C) 2001 Elsevier Science Ltd. All rights reserved.
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页码：399 / 403
页数：5
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