Sulfoxides in the allylation of aldehydes in the presence of silicon tetrachloride and allyltributylstannane

被引：8

作者：

Massa, Antonio ^{[1
]}

Capozzolo, Laura ^{[1
]}

Scettri, Arrigo ^{[1
]}

机构：

[1] Univ Salerno, Dept Chem, I-84084 Salerno, Italy

来源：

CENTRAL EUROPEAN JOURNAL OF CHEMISTRY | 2010年 / 8卷 / 06期

关键词：

Allylation of aldehydes; Sulfoxides; Lewis base; Silicon tetrachloride; Allyltributylstannane; LEWIS-BASE ACTIVATION; ALDOL ADDITION-REACTIONS; PASSERINI-TYPE REACTIONS; SILYL KETENE ACETALS; ASYMMETRIC ALLYLATION; CHIRAL SULFOXIDES; ENANTIOSELECTIVE ALLYLATION; ORGANIC-SYNTHESIS; ALPHA-ADDITIONS; MESO-EPOXIDES;

D O I：

10.2478/s11532-010-0099-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

SiCl(4) can be conveniently activated by catalytic amounts of dimethyl sulfoxide or other readily-available sulfoxides for the allylation of aromatic, hetero-aromatic and unsaturated aldehydes in the presence of allyltributyl stannane. Chiral aryl methyl sulfoxides have been used to develop asymmetric allylation methods, as well as probe the aldehyde substrate scope.

引用

页码：1210 / 1215

页数：6

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