Finite size dependence of the tracer surface diffusion coefficient near a second order phase transition

被引:9
|
作者
Nieto, F
Uebing, C
机构
[1] Max Planck Inst Eisenforsch GmbH, D-40237 Dusseldorf, Germany
[2] Univ Dortmund, Lehrstuhl Phys Chem 2, D-44227 Dortmund, Germany
[3] Univ Nacl San Luis, CONICET, Dept Fis, RA-5700 San Luis, Argentina
[4] Univ Nacl San Luis, CONICET, Ctr Latino Amer Estud Ilya Prigogine, RA-5700 San Luis, Argentina
来源
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1998年 / 102卷 / 07期
关键词
computer experiments; critical phenomena; diffusion; phase transitions; surfaces;
D O I
10.1002/bbpc.19981020711
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate the finite size dependences of the tracer surface diffusion coefficient in the vicinity of a second order phase transition. For this purpose, we use a lattice gas model of repulsively interacting particles on a square lattice. For all lattice sizes L studied, the tracer diffusion coefficient, D-t, is a smooth function of temperature. There are no anomalies in the direct temperature dependence of D-t near the critical temperature T-c. However, its derivative, dD(t)/d(1/k(B)T), exhibits cusp-like anomalies which are largely pronounced for large lattice sizes.
引用
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页码:974 / 977
页数:4
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