Realizing the Photoene Reaction with Alkenes under Visible Light Irradiation and Bypassing the Favored [2+2]-Photocycloaddition

被引:23
|
作者
Ahuja, Sapna [1 ,2 ]
Raghunathan, Ramya [3 ]
Kumarasamy, Elango [3 ]
Jockusch, Steffen [3 ]
Sivaguru, Jayaraman [1 ,2 ]
机构
[1] Bowling Green State Univ, Ctr Photochem Sci, Bowling Green, OH 43403 USA
[2] Bowling Green State Univ, Dept Chem, Bowling Green, OH 43403 USA
[3] Columbia Univ, Dept Chem, New York, NY 10027 USA
基金
美国国家科学基金会;
关键词
NON-BIARYL ATROPISOMERS; PATERNO-BUCHI REACTION; ENE REACTIONS; ORGANIC-SYNTHESIS; SINGLET OXYGEN; PHOTOCYCLOADDITION;
D O I
10.1021/jacs.8b08100
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The textbook photoreaction between two alkenes is the [2 + 2]-photocycloaddition resulting in functionalized cyclobutanes. Herein, we disclose an unusual reactivity of alkenes that favor photoene reaction over the [2 + 2]-photocycloaddition.
引用
收藏
页码:13185 / 13189
页数:5
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