Realizing the Photoene Reaction with Alkenes under Visible Light Irradiation and Bypassing the Favored [2+2]-Photocycloaddition

被引：23
|
作者：
Ahuja, Sapna [1 ,2 ]
Raghunathan, Ramya [3 ]
Kumarasamy, Elango [3 ]
Jockusch, Steffen [3 ]
Sivaguru, Jayaraman [1 ,2 ]
机构：
[1] Bowling Green State Univ, Ctr Photochem Sci, Bowling Green, OH 43403 USA
[2] Bowling Green State Univ, Dept Chem, Bowling Green, OH 43403 USA
[3] Columbia Univ, Dept Chem, New York, NY 10027 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2018年 / 140卷 / 41期
基金：
美国国家科学基金会;
关键词：
NON-BIARYL ATROPISOMERS; PATERNO-BUCHI REACTION; ENE REACTIONS; ORGANIC-SYNTHESIS; SINGLET OXYGEN; PHOTOCYCLOADDITION;
D O I：
10.1021/jacs.8b08100
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The textbook photoreaction between two alkenes is the [2 + 2]-photocycloaddition resulting in functionalized cyclobutanes. Herein, we disclose an unusual reactivity of alkenes that favor photoene reaction over the [2 + 2]-photocycloaddition.
引用
收藏
页码：13185 / 13189
页数：5
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