Synthesis and structural characterization of a Pd2+ complex with p-tert-butylsulfinylcalix[4]arene

被引:29
|
作者
Morohashi, N
Iki, N
Miyano, S
Kajiwara, T
Ito, T
机构
[1] Tohoku Univ, Grad Sch Engn, Dept Biomol Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan
[2] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan
关键词
D O I
10.1246/cl.2001.66
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Single-crystal X-ray analysis has shown that p-tert-butyl-sulfinylcalix[4]arene (H4L) can bind Pd2+ ion by using either S or O atoms of bridging S=O groups in addition to phenolic oxy gen atoms to form in [Pd-2(H2L)(H3L)(2)] complex.
引用
收藏
页码:66 / 67
页数:2
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