The localized-to-delocalized transition in mixed-valence chemistry

被引：944
|
作者：
Demadis, KD
Hartshorn, CM
Meyer, TJ
机构：
[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA
[2] Univ N Carolina, Dept Chem, Venable Lab, Chapel Hill, NC 27599 USA
[3] Univ N Carolina, Dept Chem, Kenan Lab, Chapel Hill, NC 27599 USA
来源：
CHEMICAL REVIEWS | 2001年 / 101卷 / 09期
关键词：
D O I：
10.1021/cr990413m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The analysis and catagorization of the transition between localization and delocalization in ligand-bridged, mixed-valence molecules were discussed. Transition metal complexes were used. Results showed that the molecules reveal the extraordinarily subtle nuances that can be displayed by real mixed-valence molecules in the localized-to-delocalized transition. A new class of mixed-valence molecules were also found.
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页码：2655 / 2685
页数：31
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