Treatment of Rare-Earth Concentrate to Remove Phosphorus and Fluorine Compounds

被引:5
|
作者
Lokshin, E. P. [1 ]
Tareeva, O. A. [1 ]
机构
[1] Russian Acad Sci, Tananaev Inst Chem & Technol Rare Elements & Mine, Kola Sci Ctr, Apatity, Murmansk Oblast, Russia
关键词
Water Leaching; Lanthanide Concentrate; Hydrated Silica; Sodium Compound; Sulfuric Acid Treatment;
D O I
10.1134/S1070427210110042
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
It was suggested to purify poor lanthanide concentrate precipitated from the extraction orthophosphoric acid produced by the dihydrate process to remove phosphorus and fluorine compounds by heating a mixture of the concentrate with sulfuric acid in the presence of hydrated silica followed by water leaching of water-soluble sulfates and phosphates. The treatment conditions for the separation of the bulk of phosphorus( V) and the entire fluorine in the form of SiF(4) were determined, ensuring approximately 3.5-fold increase in lanthanide concentration.
引用
收藏
页码:1919 / 1924
页数:6
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