A mechanism for production of singlet oxygen by acidification of hypochlorite

被引：5

作者：

Jacobsen, Jan ^{[1
]}

Jensen, Svend J. Knak ^{[1
]}

机构：

[1] Univ Aarhus, Dept Chem, DK-8000 Aarhus C, Denmark

来源：

CHEMICAL PHYSICS LETTERS | 2007年 / 449卷 / 1-3期

关键词：

D O I：

10.1016/j.cplett.2007.10.056

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A mechanism for the production of singlet oxygen by acidification of hypochlorite in aqueous solution is proposed based on electron structure calculations. The mechanism involves two transition states and a peroxyhypochlorous acid intermediate. The calculations include six explicit water molecules to give some allowance for solvation of the produced electrolyte. The theoretical level is the density functional theory and the isodensity polarized continuum method. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：135 / 137

页数：3

共 50 条

[21] SINGLET OXYGEN PRODUCTION BY HUMAN EOSINOPHILS
KANOFSKY, JR
HOOGLAND, H
WEVER, R
WEISS, SJ
JOURNAL OF BIOLOGICAL CHEMISTRY, 1988, 263 (20) : 9692 - 9696
[22] CHEMISTRY OF SINGLET OXYGEN .4. OXYGENATIONS WITH HYPOCHLORITE-HYDROGEN PEROXIDE
FOOTE, CS
WEXLER, S
ANDO, W
HIGGINS, R
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (04) : 975 - &
[23] Effect of proline on the production of singlet oxygen
Alia
Mohanty, P
Matysik, J
AMINO ACIDS, 2001, 21 (02) : 195 - 200
[24] Electrochemical Monitoring of Singlet Oxygen Production
Sharp, Duncan
Forsythe, Stephen
Davis, James
ELECTROANALYSIS, 2009, 21 (21) : 2293 - 2296
[25] SINGLET OXYGEN GENERATION FROM SODIUM-HYPOCHLORITE AND HYDROGEN-PEROXIDE
MITCHELL, E
QUON, M
GRUNINGER, SE
SIEW, C
JOURNAL OF DENTAL RESEARCH, 1983, 62 : 280 - 280
[26] AEROSOL GENERATORS FOR SINGLET OXYGEN PRODUCTION
BLAUER, JA
MUNJEE, SA
TRUESDELL, KA
CURTIS, EC
SULLIVAN, JF
JOURNAL OF APPLIED PHYSICS, 1987, 62 (06) : 2508 - 2517
[27] Singlet delta oxygen production in a slab discharge in oxygen
Ionin, Andrey A.
Frolov, Mikhail P.
Kochetov, Igor V.
Ochkin, Vladimir N.
Napartovich, Anatoly P.
Podmar'kov, Yurii P.
Rulev, Oleg A.
Savinov, Sergey Yu.
Seleznev, Leonid V.
Sinitsyn, Dmitry V.
Vagin, Nikolay P.
Yuryshev, Nikolay N.
XVI INTERNATIONAL SYMPOSIUM ON GAS FLOW, CHEMICAL LASERS, AND HIGH-POWER LASERS, PTS 1 AND 2, 2007, 6346
[28] Production of singlet oxygen in the benzene oxygen photochemical system
Snelling, D. R.
CHEMICAL PHYSICS LETTERS, 1968, 2 (05) : 346 - 348
[29] Insights into the Mechanism of Quantum Dot-Sensitized Singlet Oxygen Production for Photodynamic Therapy
Charron, Gaelle
Stuchinskaya, Tanya
Edwards, Dylan R.
Russell, David A.
Nann, Thomas
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (16): : 9334 - 9342
[30] Mechanism for Singlet Oxygen Production in Li-Ion and Metal-Air Batteries
Houchins, Gregory
Pande, Vikram
Viswanathan, Venkatasubramanian
ACS ENERGY LETTERS, 2020, 5 (06) : 1893 - 1899

← 1 2 3 4 5 →