Observation of the (A)over-tilde-(X)over-tilde electronic transition of the CF3O2 radical

被引：19
|
作者：
Zalyubovsky, SJ [1 ]
Wang, DB [1 ]
Miller, TA [1 ]
机构：
[1] Ohio State Univ, Dept Chem, Laser Spect Facil, Columbus, OH 43210 USA
来源：
CHEMICAL PHYSICS LETTERS | 2001年 / 335卷 / 3-4期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/S0009-2614(01)00058-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The first observation of a sharp, structured electronic spectrum for a fluorinated alkyl peroxy radical is reported using the technique of cavity ringdown spectroscopy (CRDS). The Tao value for the (A) over tilde (2)A' -(X) over tilde (2)A " transition of CF3O2 has been determined to be 6656(3) cm(-1) values for (A) over tilde state vibrational frequencies have also been determined. Initial kinetic observations on CF3O2 have been carried out, using CRDS to monitor its concentration. (C) 2001 Published by Elsevier Science B.V.
引用
收藏
页码：298 / 304
页数：7
相关论文
共 50 条
  • [21] Algebraic solution of fuzzy linear system as: (A)over-tilde(X)over-tilde + (B)over-tilde(X)over-tilde = (Y)over-tilde
    Allahviranloo, T.
    Babakordi, F.
    SOFT COMPUTING, 2017, 21 (24) : 7463 - 7472
  • [22] Rotationally resolved (B)over-tilde-(X)over-tilde electronic spectra of both conformers of the 1-propoxy radical
    Gopalakrishnan, S
    Carter, CC
    Zu, L
    Stakhursky, V
    Tarczay, G
    Miller, TA
    JOURNAL OF CHEMICAL PHYSICS, 2003, 118 (11): : 4954 - 4969
  • [23] Observation of the (A)over-tilde-(X)over-tilde Electronic Transitions of Cyclopentyl and Cyclohexyl Peroxy Radicals via Cavity Ringdown Spectroscopy
    Thomas, Phillip S.
    Chhantyal-Pun, Rabi
    Miller, Terry A.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2010, 114 (01): : 218 - 231
  • [24] OBSERVATION AND ANALYSIS OF ROTATIONALLY RESOLVED (B)OVER-TILDE-(X)OVER-TILDE ELECTRONIC-TRANSITIONS OF CD-AR
    MCQUAID, MJ
    LEMIRE, GW
    SAUSA, RC
    CHEMICAL PHYSICS LETTERS, 1993, 210 (4-6) : 350 - 354
  • [25] Laser excitation and dispersed fluorescence spectra of the HCBr (A)over-tilde-(X)over-tilde vibronic transition
    Tsai, TC
    Chen, CW
    Chang, BC
    JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (02): : 766 - 770
  • [26] Laser induced fluorescence spectroscopy of the (A)over-tilde 3Πi←(X)over-tilde 3Σ- transition of the CCS radical
    Schoeffler, AJ
    Kohguchi, H
    Hoshina, K
    Ohshima, Y
    Endo, Y
    JOURNAL OF CHEMICAL PHYSICS, 2001, 114 (14): : 6142 - 6150
  • [27] Universal algebraic solution of the interval linear system: (A)over-tilde(X)over-tilde + (B)over-tilde(X)over-tilde = (Y)over-tilde
    Piegat, Andrzej
    Plucinski, Marcin
    KNOWLEDGE-BASED AND INTELLIGENT INFORMATION & ENGINEERING SYSTEMS (KSE 2021), 2021, 192 : 526 - 532
  • [28] Fourier transform emission spectrum of the HCSi radical, (A)over-tilde 2Σ+-(X)over-tilde 2Πi transition
    Cireasa, R
    Cossart, D
    Vervloet, M
    Robbe, JM
    JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (24): : 10806 - 10810
  • [29] Dispersed fluorescence spectrum of the HC35Cl(A)over-tilde-(X)over-tilde vibronic transition
    Chen, CW
    Tsai, TC
    Chang, BC
    CHEMICAL PHYSICS LETTERS, 2001, 347 (1-3) : 73 - 78
  • [30] Dispersed fluorescence spectra of the CCl2 (A)over-tilde-(X)over-tilde vibronic bands
    Liu, ML
    Lee, CL
    Bezant, A
    Tarczay, G
    Clark, RJ
    Miller, TA
    Chang, BC
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (07) : 1352 - 1358
12345