Synthesis and quantum-chemical study of germanium-containing 2,6-bis(hydroxymethyl)pyridine derivatives

被引：0
|
作者：
Churakov, AV
Karlov, SS
Yakubova, EK
Selina, AA
Zabalov, MV
Oprunenko, YF
Zaitseva, GS
机构：
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Moscow 119992, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 50卷 / 10期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Germanium tetrahalides (GeCl4, GeBr4) react with bis(trimethylsilyl) ether of 2,6-bis(hydroxymethyl)pyridine (2,6-C5H3N(CH2OSiMe3)(2) to give the corresponding dihalogermanes 2,6-C5H3(CH2O)(2)GeHal(2) (Hal = Cl, Br), the first germanium-containing 2,6-bis(hydroxymethyl)pyridine derivatives. The structure of the products is supported by elemental analysis, H-1 and C-13 NMR, and mass spectrometry data. Comparison of the geometrical parameters of 2,6-C5H3(CH2O)(2)GeHal(2) calculated by the density functional theory method with the experimental and calculated values for the analogous silicon and tin compounds makes it possible to formulate the basic structural features of element-containing pyridine-based macrocycles.
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页码：1511 / 1515
页数：5
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