Helical mono and dinuclear mercury(II) N-heterocyclic carbene complexes

被引：73
|
作者：
Lee, KM [1 ]
Chen, JCC [1 ]
Lin, IJB [1 ]
机构：
[1] Fu Jen Catholic Univ, Dept Chem, Taipei 24205, Taiwan
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 617卷 / 01期
关键词：
carbene complexes; double helicates; supramolecules; mercury;
D O I：
10.1016/S0022-328X(00)00617-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of mono and dicationic carbene precursors have been synthesized. Reactions of these precursors with Hg(OAc)(2) produce helical mononuclear and dinuclear mercury(II) carbene complexes. Five structures, including two ligand precursors and three mercury(II) carbene complexes have been analyzed by single crystal X-ray diffraction. Several intermediates have been identified during the course of reaction. Based on these observed intermediates, three different reaction pathways have been proposed. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：364 / 375
页数：12
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