Two-photon polymerization of titanium-containing sol-gel composites for three-dimensional structure fabrication

被引：59
|
作者：
Sakellari, I. [1 ,3 ]
Gaidukeviciute, A. [1 ,4 ]
Giakoumaki, A. [1 ,5 ]
Gray, D. [1 ]
Fotakis, C. [1 ,3 ]
Farsari, M. [1 ]
Vamvakaki, M. [1 ,5 ]
Reinhardt, C. [1 ,2 ]
Ovsianikov, A. [2 ]
Chichkov, B. N. [1 ,2 ]
机构：
[1] Fdn Res & Technol Hellas FORTH, Inst Elect Struct & Laser, Iraklion 71110, Crete, Greece
[2] Laser Zentrum Hannover EV, Nanotechnol Dept, D-30419 Hannover, Germany
[3] Univ Crete, Dept Phys, Iraklion, Crete, Greece
[4] Leibniz Univ Hannover, Hannover, Germany
[5] Univ Crete, Dept Mat Sci & Technol, Iraklion, Crete, Greece
来源：
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2010年 / 100卷 / 02期
关键词：
PHOTONIC-CRYSTAL; PHOTOCATALYTIC ACTIVITY; OPTICAL-PROPERTIES; HYBRID MATERIALS; MICROFABRICATION; SILICA; FILMS;
D O I：
10.1007/s00339-010-5864-0
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In this work, we have synthesized and characterized a novel, titanium-containing hybrid material that can be structured three-dimensionally using two-photon polymerization. We investigate the effect on the structurability of the increase of titanium isopropoxide and methacrylic acid in this photosensitive composite. We show that while it is possible to make transparent thin films with a titanium isopropoxide molar content as high as 90%, three-dimensional structures can be made only when the titanium isopropoxide molar content is less than 50%. We measure the refractive index of films with different titanium isopropoxide: methacrylic acid concentrations and we show that while the refractive index increases linearly with the titanium isopropoxide, the increase of the methacrylic acid content does not affect the refractive index of the material.
引用
收藏
页码：359 / 364
页数：6
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