Preparation and properties of semifluorinated block copolymers of 2-(dimethylamino)ethyl methacrylate and fluorooctyl methacrylates

被引：28
|
作者：
Hwang, HS
Heo, JY
Jeong, YT
Jin, SH
Cho, D
Chang, T
Lim, KT
机构：
[1] Pukyong Natl Univ, Div Image & Informat Engn, Pusan 608739, South Korea
[2] Pusan Natl Univ, Dept Chem Educ, Pusan 609735, South Korea
[3] Pohang Univ Sci & Technol, Dept Chem, Pohang 790784, South Korea
[4] Pohang Univ Sci & Technol, Polymer Res Inst, Pohang 790784, South Korea
来源：
POLYMER | 2003年 / 44卷 / 18期
关键词：
block copolymer; micelle; semifluorinated copolymer;
D O I：
10.1016/S0032-3861(03)00566-4
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Semifluorinated block copolymers of poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) and poly(fluorooctyl methacrylates) (PFOMA) were prepared using group transfer polymerisation via sequential monomer addition. Wide ranges of copolymers were obtained with good control over both molecular weight and composition by adjusting the monomers/initiator ratio. The micellar characteristics of the copolymers in water and chloroform were investigated by quasi-elastic light scattering and transmission electron microscopy. The size and morphologies of micelles were greatly influenced by copolymer composition, pH, and temperature. In addition, the solubility of copolymers and the formation of water-in-carbon dioxide (W/C) microemulsions were described in terms of the cloud points. The block copolymers exhibited the excellent ability of stabilizing W/C microemulsions. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5153 / 5158
页数：6
相关论文
共 50 条
  • [31] Synthesis and characterization of original 2-(dimethylamino)ethyl methacrylate/poly(ethyleneglycol) star-copolymers
    Shim, Yong-Ho
    Bougard, Francois
    Coulembier, Olivier
    Lazzaroni, Roberto
    Dubois, Philippe
    EUROPEAN POLYMER JOURNAL, 2008, 44 (11) : 3715 - 3723
  • [32] Azeotropic atom transfer radical polymerization of hydroxyethyl methacrylate and (dimethylamino)ethyl methacrylate statistical copolymers and block copolymers with polystyrene
    Guice, KB
    Loo, YL
    MACROMOLECULES, 2006, 39 (07) : 2474 - 2480
  • [33] Formation of silver nanoparticles in 2-(dimethylamino)ethyl methacrylate
    Sergeev, BM
    Kasaikin, VA
    Litmanovich, EA
    Sergeev, GB
    COLLOID JOURNAL, 1999, 61 (05) : 662 - 664
  • [34] Antifungal properties of poly[2-(dimethylamino)ethyl methacrylate] (PDMAEMA) and quaternized derivatives
    De Jesus-Tellez, Marco A.
    De la Rosa-Garcia, Susana
    Medrano-Galindo, Itzel
    Rosales-Penafiel, Ingrid
    Gomez-Cornelio, Sergio
    Guerrero-Sanchez, Carlos
    Schubert, Ulrich S.
    Quintana-Owen, Patricia
    REACTIVE & FUNCTIONAL POLYMERS, 2021, 163
  • [35] ANIONIC POLYMERIZATION OF 2-METHOXYETHYL METHACRYLATE AND 2-(DIMETHYLAMINO)ETHYL METHACRYLATE
    TREKOVAL, J
    VLCEK, P
    LIM, D
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1971, 36 (08) : 3032 - &
  • [36] Ultra-thin films of cationic amphiphilic poly(2-(dimethylamino)ethyl methacrylate) based block copolymers as surface wettability modifiers
    Nurmi, Leena
    Holappa, Susanna
    Nykanen, Antti
    Laine, Janne
    Ruokolainen, Janne
    Seppala, Jukka
    POLYMER, 2009, 50 (22) : 5250 - 5261
  • [37] Thermosensitive Behavior of Poly(ethylene glycol)/Poly(2-(N,N-dimethylamino)ethyl methacrylate) Double Hydrophilic Block Copolymers
    Dong, Anjie
    Zhai, Yinglei
    Xiao, Li
    Qi, Haiying
    Tian, Qi
    Deng, Liandong
    Guo, Ruiwei
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2010, 48 (05) : 503 - 508
  • [38] Reversible addition-fragmentation chain transfer polymerization of 2-(dimethylamino)ethyl methacrylate/2-(dimethylamino)ethyl acrylate
    Xin, XQ
    Wang, YM
    Pan, CY
    ACTA POLYMERICA SINICA, 2005, (03) : 398 - 402
  • [39] Copolymers of 2-(dimethylamino)ethyl methacrylate with ethoxytriethylene glycol methacrylate or N-vinyl-pyrrolidone as gene transfer agents
    van de Wetering, P
    Schuurmans-Nieuwenbroek, NME
    van Steenbergen, MJ
    Crommelin, DJA
    Hennink, WE
    JOURNAL OF CONTROLLED RELEASE, 2000, 64 (1-3) : 193 - 203
  • [40] Copolymers of 4-Fluoro Benzyl Methacrylate and 2-(Dimethylamino)ethyl Methacrylate: Reactivity Ratios, Thermal Properties, Biologial Activity, and Semi-Conducting Properties
    Erol, Ibrahim
    Arslanturk, Busra
    Gurler, Zeki
    POLYMER SCIENCE SERIES B, 2015, 57 (03) : 228 - 238
12345