Porous Pt-Ni-P Composite Nanotube Arrays: Highly Electroactive and Durable Catalysts for Methanol Electrooxidation

被引:374
|
作者
Ding, Liang-Xin [1 ]
Wang, An-Liang [1 ]
Li, Gao-Ren [1 ]
Liu, Zhao-Qing [1 ]
Zhao, Wen-Xia [1 ]
Su, Cheng-Yong [1 ]
Tong, Ye-Xiang [1 ]
机构
[1] Sun Yat Sen Univ, MOE Lab Bioinorgan & Synthet Chem, KLGHEI Environm & Energy Chem, Sch Chem & Chem Engn,Instrumental Anal & Res Ctr, Guangzhou 510275, Guangdong, Peoples R China
关键词
OXYGEN REDUCTION REACTION; ENHANCED ELECTROCATALYTIC ACTIVITY; METAL-FREE ELECTROCATALYSTS; CORE-SHELL; BIMETALLIC NANODENDRITES; PLATINUM NANOCRYSTALS; FACILE SYNTHESIS; MONO LAYER; CARBON; PERFORMANCE;
D O I
10.1021/ja212206m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Porous Pt-Ni-P composite nanotube arrays (NTAs) on a conductive substrate in good solid contact are successfully synthesized via template-assisted electrodeposition and show high electrochemical activity and long-term stability for methanol electrooxidation. Hollow nanotubular structures, porous nanostructures, and synergistic electronic effects of various elements contribute to the high electrocatalytic performance of porous Pt-Ni-P composite NTA electrocatalysts.
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页码:5730 / 5733
页数:4
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