Formation and hetero Diels-Alder reaction of α-iminosulfines:: Synthesis of 5,6-dihydro-1,4-thiazine S-oxides

被引：0

作者：

Capozzi, G ^{[1
]}

Menichetti, S ^{[1
]}

Nativi, C ^{[1
]}

Vergamini, C ^{[1
]}

机构：

[1] Univ Florence, Dipartimento Chim Organ, CNR, Ctr Chim Composti Eterocicl, I-50121 Florence, Italy

来源：

SYNTHESIS-STUTTGART | 1998年 / 06期

关键词：

hetero Diels-Alder; electron-poor dienes; alpha-imino thioketone S-oxides; 1,4-thiazines;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Simple transformations of anthracene derived cycloadduct 1 allows the in situ generation of alpha-iminosulfines (alpha-imino thioketone S-oxides), a new class of sulfur-nitrogen substituted electron-poor dienes useful for the synthesis of the 1,4-thiazine S-oxide ring system.

引用

页码：915 / 918

页数：4

共 50 条

[21] Synthesis of (+,-) 3,4-disubstituted 3,4-dihydro-2H-thiopyrans via a diastereoselective hetero Diels-Alder reaction
Marchand, A
Pradere, JP
Guingant, A
TETRAHEDRON LETTERS, 1997, 38 (06) : 1033 - 1036
[22] Synthesis of Tetrahydropyrazolo[4′,3′:5,6]pyrano[3,4-c]quinolones by Domino Knoevenagel/Hetero Diels-Alder Reactions
Kiamehr, Mostafa
Mohammadkhani, Leyla
Khodabakhshi, Mohammad Reza
Jafari, Behzad
Langer, Peter
SYNLETT, 2019, 30 (15) : 1782 - 1786
[23] SYNTHESIS OF ANTHRACYCLINONE INTERMEDIATES - DIELS-ALDER REACTION AND [1,5]-REARRANGEMENTS OF SOME BENZOYL-1,4-BENZOQUINONES
CHAUDHARY, B
POKHARNA, CP
PRASHANT, A
PARDASANI, RT
SINGH, P
PHARMAZIE, 1993, 48 (12): : 943 - 944
[24] Formation of derivatives of 5,6-dihydro-1,3-thiazines in the reaction of acetothioacetic acid ethyl ester under the conditions of the hantzsch synthesis
Vigante B.
Ozols J.
Mishnev A.
Duburs G.
Chekavichus B.
Chemistry of Heterocyclic Compounds, 2000, 36 (7) : 862 - 869
[25] A SHORT-STEP SYNTHESIS OF ONYCHINE AND THE RELATED 4-AZAFLUORENONES ⁢VIA⁢ HETERO DIELS-ALDER REACTION OF 5-SUBSTITUTED ISOTELLURAZOLES
Taneichi, Yusuke
Shimada, Kazuaki
Korenaga, Toshinobu
HETEROCYCLES, 2018, 96 (03) : 440 - 451
[26] An efficient synthesis of thiopyrano[5,6-c]coumarin/[6,5-c]-chromones through intramolecular domino Knoevenagel hetero Diels-Alder reactions
Jayashankaran, J
Manian, RDRS
Raghunathan, R
TETRAHEDRON LETTERS, 2006, 47 (13) : 2265 - 2270
[27] 5-Phenylthio-1,3-oxazinan-4-ones via hetero Diels-Alder reactions:: synthesis of (R)- and (S)-duloxetines and fluoxetines
Panunzio, Mauro
Tamanini, Emiliano
Bandini, Elisa
Campana, Eileen
D'Aurizio, Antonio
Vicennati, Paola
TETRAHEDRON, 2006, 62 (52) : 12270 - 12280
[28] DIASTEREOFACIAL SELECTIVITY IN THE DIELS-ALDER REACTION OF 5(S)-E-5,6-O-ISOPROPYLIDEN-HEX-3-EN-2-ONE WITH CYCLOPENTADIENE
GALLEY, G
MUGGE, C
JONES, PG
PATZEL, M
TETRAHEDRON-ASYMMETRY, 1995, 6 (09) : 2313 - 2318
[29] Structurally Divergent Synthesis of Azetidines, 5,6-Dihydro-1,3-oxazines and 2,3-Dihydro-1,4-oxazines through Palladium-Catalyzed Tandem Allylic Substitution Reaction
Meng, Ru-Fang
Kong, Yu-Juan
Wu, Xiao-Yan
Zhang, Huan
Wang, Wei
Liang, Wen-Jie
Zheng, Lan
Lin, Chenxiang
Su, Wei
Xiao, Jun-An
CHINESE JOURNAL OF CHEMISTRY, 2024, 42 (22) : 2773 - 2778
[30] alpha-oxosulfines .1. Reactivity of alpha-oxosulfines obtained from Retro Diels-Alder reaction of 1,4-oxathiin-S-oxides.
Capozzi, G
Fratini, P
Menichetti, S
Nativi, C
TETRAHEDRON, 1996, 52 (37) : 12233 - 12246

← 1 2 3 4 5 →