SiC Ceramic-Bonded Carbon Fabricated With Si3N4 and Carbon Powders

被引:11
|
作者
Chen, Weiwu [1 ]
Tojo, Tetsuro [1 ,2 ]
Miyamoto, Yoshinari [1 ,2 ]
机构
[1] Osaka Univ, Joining & Welding Res Inst, Ibaraki, Osaka 5670047, Japan
[2] Toyo Tanso Co Ltd, Adv Carbon Technol Ctr, Nishiyodogawa Ku, Osaka 5550011, Japan
关键词
THERMAL-CONDUCTIVITY;
D O I
10.1111/j.1744-7402.2011.02677.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
New composites called ceramic-bonded carbon (CBCs), consisting of a three-dimensional structure of carbon particles bonded with thin ceramic boundaries, were developed. To fabricate light and tough CBCs and to understand their reinforcing mechanism, Si3N4 and carbon powders (25:75 in volume ratio) were gelcasted and then sintered by spark plasma sintering at temperatures of 17001900 degrees C. The ceramic boundary of SiC was formed in situ at above 1700 degrees C by the reaction of Si3N4 and C. The sintered CBCs showed a unique microstructure consisting of carbon particles and ceramic boundaries of 15 similar to mu m in size and 0.53 similar to mu m in thickness, respectively. With an increase in sintering temperature, physical bonding of ceramic grains to the carbon particles was enhanced as the grain growth of SiC increased. The SiC/CBCs sintered at 1900 degrees C were highly dense (97% theoretical density), lightweight (2.36 similar to mg/m3), and had both relatively high bending strength and thermal conductivity (135 similar to MPa and 140 similar to W/mK, respectively).
引用
收藏
页码:313 / 321
页数:9
相关论文
共 50 条
  • [21] Nano-indentation of SiC and Si3N4/SiC ceramic materials
    Balog, M
    Sajgalík, P
    Lencés, Z
    Hnatko, M
    Keckes, J
    Huang, JL
    Janega, J
    Horváthová, R
    FRACTOGRAPHY OF ADVANCED CERAMICS II, 2005, 290 : 272 - 275
  • [22] Bonding properties of joining Si3N4/SiC ceramic by SiC adhesive
    National Key Laboratory of Thermostructure Composite Materials, Northwestern Polytechnical University, Xi'an 710072, China
    Cailiao Gongcheng, 2006, 8 (23-27+32):
  • [23] CNTs/Si3N4 composites fabricated by reaction bonded processing
    Huang, Zhi-Yong
    Liu, Xue-Jian
    Sun, Xing-Wei
    Huang, Li-Ping
    HIGH-PERFORMANCE CERAMICS IV, PTS 1-3, 2007, 336-338 : 1277 - 1279
  • [24] SI3N4/SiC composites using conventional and nanosized powders
    Kaiser, A
    Vassen, R
    Stover, D
    Buchkremer, HP
    Forster, J
    Uhlenbusch, J
    NANOSTRUCTURED MATERIALS, 1995, 6 (5-8): : 917 - 920
  • [25] DISPERSION AND PACKING OF MIXTURES OF SI3N4 POWDERS WITH SIC WHISKERS
    ALMEIDA, JCM
    SACRAMENTO, JMG
    CORREIA, RN
    FONSECA, AT
    BAPTISTA, JL
    FABRICATION TECHNOLOGY, 1989, 45 : 179 - 186
  • [26] PREPARATION OF SIC AND SI3N4 POWDERS BY RF-PLASMA
    KUIBIRA, A
    MITSUI, A
    HOJO, J
    KATO, A
    YOGYO-KYOKAI-SHI, 1987, 95 (01): : 89 - 91
  • [27] Thermal shock resistance of Si3N4/SiC nanocomposites fabricated from amorphous Si-C-N precursor powders
    Hirano, T
    Niihara, K
    MATERIALS LETTERS, 1996, 26 (06) : 285 - 289
  • [28] Surface modification of Si3N4 ceramic powders by emulsion polymerization
    Yan, LT
    Si, WJ
    Miao, HZ
    RARE METAL MATERIALS AND ENGINEERING, 2002, 31 : 5 - 7
  • [29] Machining of green Si3N4 polymer bonded ceramic materials
    Scheller, WL
    Wanmuhamad, W
    MATERIALS AND MANUFACTURING PROCESSES, 1996, 11 (05) : 775 - 787
  • [30] Properties of reaction-bonded SiC/Si3N4 ceramics
    Luo Fa
    Zhu Dongmei
    Zhang Hua
    Zhou Wancheng
    MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 431 (1-2): : 285 - 289