N-donor ligand complexes of nickel, zinc and copper: Comparisons with tetradentate N-donor ligands derived from Schiff bases

被引：10
|
作者：
Mustapha, Abdullahi [2 ]
Duckmanton, Paul [1 ]
Reglinski, John [1 ]
Kennedy, Alan R. [1 ]
机构：
[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland
[2] Kano Univ Sci & Technol, Dept Chem, Wudil, Kano State, Nigeria
来源：
POLYHEDRON | 2010年 / 29卷 / 13期
关键词：
Multidentate; Hydrogenated Schiff base; Nickel; Zinc Copper; CRYSTAL-STRUCTURE; ELECTROCHEMICAL SYNTHESIS; IMINE LIGANDS; PERCHLORATE; GEOMETRY; NITRATE; IONS; SPIN;
D O I：
10.1016/j.poly.2010.06.001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The nickel and zinc complexes of 2-aminomethylaniline (AMA) are reported. Both metals form the octahedral complex [M(AMA)(2)(ONO2)(2)] (M = Ni, Zn) where the aromatic ligands lie in the meridial plane with the anilino donors trans to one another. The remaining nitrates coordinate axially. A simple comparison with the nitrogen donor disposition (cis/trans) in nickel complexes of tetradentate N-4 donor ligands derived from symmetric Schiff base ligands is presented. The discussion is extended to interrogate the bonding motifs of the nitrate ligands viz -ONO2 in the nickel complexes of AMA compared to the two motifs (viz O2NO and ONO2) that are isolated for the nickel complexes of the macrocycle hexamethyltetraazacyclotetradecane. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2590 / 2594
页数：5
相关论文
共 50 条
  • [21] Structural Characterization of Two Copper(II) Bishexafluoroacetylacetonate Complexes with N-Donor Ligands
    Wang, Y. -C.
    Wang, G. -F.
    Liu, Z. -R.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 59 (03) : 733 - 738
  • [22] Synthesis and structural characterization of copper(II) bishexafluoroacetylacetonate complexes with N-donor ligands
    Delgado, S
    Muñoz, A
    Medina, ME
    Pastor, CJ
    [J]. INORGANICA CHIMICA ACTA, 2006, 359 (01) : 109 - 117
  • [23] Nitric oxide sensors based on copper(II) complexes of N-donor ligands
    Kumar, Pankaj
    Kalita, Apurba
    Mondal, Biplab
    [J]. INORGANICA CHIMICA ACTA, 2013, 404 : 88 - 96
  • [24] Structural Characterization of Two Copper(II) Bishexafluoroacetylacetonate Complexes with N-Donor Ligands
    Y.-C. Wang
    G.-F. Wang
    Z.-R. Liu
    [J]. Journal of Structural Chemistry, 2018, 59 : 733 - 738
  • [25] Synthesis and characterization of Ni(II) complexes of O,N-donor Schiff bases derived from acyl pyrazolone analogues
    Vyas, Komal M.
    Shah, Vrunda K.
    Jadeja, R. N.
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (06) : 1069 - 1081
  • [26] Copper(I) and silver(I) azide complexes containing N-donor ligands
    Pettinari, C
    [J]. POLYHEDRON, 2001, 20 (21) : 2755 - 2763
  • [27] Screening of antibacterial and cytotoxicity of the copper (II) complexes of N-donor chelating ligand
    Devi, A. Bimolini
    Devi, M. Damayanti
    Surbala, Laishram
    [J]. INDIAN JOURNAL OF BIOCHEMISTRY & BIOPHYSICS, 2021, 58 (06): : 582 - 589
  • [28] Ruthenium Complexes of Rigid, Dianionic, Tetradentate N-Donor Ligands and their Potential as Catalysts for Water Oxidation
    Rajabi, Sheida
    Ruettger, Franziska
    Luecken, Jana
    Dechert, Sebastian
    John, Michael
    Meyer, Franc
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 26 (03)
  • [29] REACTIONS OF BIS(ISOPROPYLXANTHATO)NICKEL(II) WITH N-DONOR LIGANDS
    TRAVNICEK, Z
    PASTOREK, R
    SINDELAR, Z
    MAREK, J
    [J]. TRANSITION METAL CHEMISTRY, 1995, 20 (01) : 67 - 71
  • [30] Synthesis, structure and luminescence behaviour of copper(II)cyanato complexes containing bidentate N-donor Schiff bases
    Chowdhury, Habibar
    Ghosh, Rajarshi
    Sarkar, Bhola Nath
    Banerjee, Sankar Prasad
    Ghosh, Barindra Kumar
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2007, 46 (09): : 1393 - 1400
12345