Energy-Intensive Random Block Copolymers of 3,3-Bis (Nitratomethyl) Oxetane and 3-Azidomethyl-3-Methyloxetane

被引：2
|
作者：
Mukhametshin, Timur I. [1 ]
Sharipov, Rail I. [1 ]
Petrov, Vladimir A. [1 ]
Kostochko, Anatoly V. [1 ]
Vinogradov, Dmitry B. [2 ]
Bulatov, Pavel V. [2 ]
机构：
[1] Inst Kazan Natl Res Technol Univ, Dept Chem & Technol Macromol Cpds, Karl Marx Str 68, Kazan 420015, Russia
[2] Russian Acad Sci, Inst ND Zelinsky Inst Organ Chem, Leninsky Prospect 47, Moscow 119334, Russia
来源：
PROPELLANTS EXPLOSIVES PYROTECHNICS | 2018年 / 43卷 / 11期
关键词：
3,3-bis (nitratomethyl) oxetane; 3-azidomethyl-3-methyloxetane; triisobutylaluminum; energy-intensive copolymers; POLY(3-AZIDOMETHYL-3-METHYL OXETANE); SUBSTITUTED OXETANES; ORGANIC NITRATES; AZIDO POLYMERS; POLYMERIZATION;
D O I：
10.1002/prep.201800216
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Copolymerization of 3,3-bis (nitratomethyl) oxetane and 3-azidomethyl-3-methyloxetane was carried out in the presence of the triisobutyl-aluminum-water catalyst system. The structure of synthesized high-molecular copolymers was proven with C-13 and H-1 NMR, IR-Fourier spectroscopy, GPC, and elemental analysis. The data on relaxation and phase transitions as well as the thermal decomposition of copolymers were obtained using the DSC method.
引用
收藏
页码：1115 / 1121
页数：7
相关论文
共 50 条
  • [21] 3,3-Bis(ETHOXYMETHYL)OXETANE.
    Hardenstine, K.E.
    Murphy, C.J.
    Jones, R.B.
    Sperling, L.H.
    Manser, G.E.
    Journal of Applied Polymer Science, 1985, 30 (05): : 2051 - 2064
  • [22] Synthesis and characterization of poly(3,3-bis(azidomethyl)oxetane-co-ε-caprolactone)s
    Jutier, JJ
    de Gunzbourg, A
    Prud'homme, RE
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1999, 37 (07) : 1027 - 1039
  • [23] Microwave Synthesis of 3,3′-Bisazidomethyl Oxetane-3-Azidomethyl-3′-Methyl Oxetane Random Copolymer
    Zhang Chi
    Li Jie
    Luo Yunjun
    Ge Zhen
    ACTA CHIMICA SINICA, 2012, 70 (04) : 492 - 498
  • [24] Effect of molecular weight on crystallization and rheological properties of poly(3,3-bis(azidomethyl)oxetane)
    B. J. Li
    Y. J. Luo
    J. Zheng
    Polymer Science, Series A, 2017, 59 : 301 - 309
  • [25] Phase Equilibrium and Interdiffusion in the Oligo(3,3-bis(azidomethyl)oxetane)-Oligo(3-methyl-3-azidomethyloxetane) System
    Kulagina, G. S.
    Badamshina, E. R.
    Mikhailov, Yu. M.
    Pisarev, S. A.
    Khasbiullin, R. R.
    Chalykh, A. E.
    POLYMER SCIENCE SERIES A, 2010, 52 (03) : 272 - 278
  • [26] Phase equilibrium and interdiffusion in the oligo(3,3-bis(azidomethyl)oxetane)-oligo(3-methyl-3-azidomethyloxetane) system
    G. S. Kulagina
    E. R. Badamshina
    Yu. M. Mikhailov
    S. A. Pisarev
    R. R. Khasbiullin
    A. E. Chalykh
    Polymer Science Series A, 2010, 52 : 272 - 278
  • [27] CHARACTERIZATION OF BLOCK COPOLYMERS BASED ON POLY[3,3-BIS(ETHOXYMETHYL)OXETANE] AND OTHER NOVEL POLYETHERS
    HARDENSTINE, KE
    MURPHY, CJ
    JONES, RB
    SPERLING, LH
    MANSER, GE
    JOURNAL OF APPLIED POLYMER SCIENCE, 1985, 30 (05) : 2051 - 2064
  • [28] SYNTHESIS AND CHARACTERIZATION OF TETRAHYDROFURAN AND 3,3-BIS(CHLOROMETHYL) OXETANE TRIBLOCK COPOLYMERS
    HSIUE, GH
    LIU, YL
    CHIU, YS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 62 - POLY
  • [29] Synthesis and Structure Characterization of 3,3′-Bisazidomethyloxetane-3-azidomethyl-3′-methyloxetane Random Copolymer
    Zhang Chi
    Li Jie
    Luo Yun-Jun
    Li Xiao-Meng
    Ge Zhen
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2011, 32 (11): : 2685 - 2690
  • [30] Poly[3,3-bis(azidomethyl)oxetane]-2,4-dinitro-2,4-diazapentane
    Pochivalov, Konstantin V.
    Kudryavtsev, Yaroslav V.
    Lebedeva, Tatyana N.
    Antina, Lyubov A.
    Ilyasova, Anna N.
    Yurov, Mikhail Yu.
    Basko, Andrey V.
    Zavadskii, Alexander E.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2018, 131 (03) : 2225 - 2233
12345