Energy-Intensive Random Block Copolymers of 3,3-Bis (Nitratomethyl) Oxetane and 3-Azidomethyl-3-Methyloxetane

被引：2

作者：

Mukhametshin, Timur I. ^{[1
]}

Sharipov, Rail I. ^{[1
]}

Petrov, Vladimir A. ^{[1
]}

Kostochko, Anatoly V. ^{[1
]}

Vinogradov, Dmitry B. ^{[2
]}

Bulatov, Pavel V. ^{[2
]}

机构：

[1] Inst Kazan Natl Res Technol Univ, Dept Chem & Technol Macromol Cpds, Karl Marx Str 68, Kazan 420015, Russia

[2] Russian Acad Sci, Inst ND Zelinsky Inst Organ Chem, Leninsky Prospect 47, Moscow 119334, Russia

来源：

PROPELLANTS EXPLOSIVES PYROTECHNICS | 2018年 / 43卷 / 11期

关键词：

3,3-bis (nitratomethyl) oxetane; 3-azidomethyl-3-methyloxetane; triisobutylaluminum; energy-intensive copolymers; POLY(3-AZIDOMETHYL-3-METHYL OXETANE); SUBSTITUTED OXETANES; ORGANIC NITRATES; AZIDO POLYMERS; POLYMERIZATION;

D O I：

10.1002/prep.201800216

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Copolymerization of 3,3-bis (nitratomethyl) oxetane and 3-azidomethyl-3-methyloxetane was carried out in the presence of the triisobutyl-aluminum-water catalyst system. The structure of synthesized high-molecular copolymers was proven with C-13 and H-1 NMR, IR-Fourier spectroscopy, GPC, and elemental analysis. The data on relaxation and phase transitions as well as the thermal decomposition of copolymers were obtained using the DSC method.

引用

页码：1115 / 1121

页数：7

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