Conjugate reactions: New potentials of an old idea

被引：4
|
作者：
Bruk, L. G. [1 ]
Temkin, O. N. [1 ]
机构：
[1] Moscow State Univ Fine Chem Technol, Moscow 119571, Russia
来源：
KINETICS AND CATALYSIS | 2016年 / 57卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
conjugate reactions; kinetic coupling; thermodynamic coupling; catalysis; chain processes; catalytic system design; VAPOR-PHASE EPOXIDATION; PROPYLENE EPOXIDATION; TANDEM CATALYSIS; CARBON-MONOXIDE; CYCLOHEXANECARBOXYLIC ACID; ACETYLENE CARBONYLATION; ALKANE DEHYDROGENATION; PALLADIUM COMPLEXES; PINCER COMPLEXES; KINETICS;
D O I：
10.1134/S0023158416030022
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Main concepts of the Shilov-Ostwald theory of conjugate chemical reactions are analyzed from the standpoint of complex reaction kinetics, theory of reaction routes, and thermodynamics of irreversible processes. Classification of conjugate reactions and an algorithm of catalytic system design for conducting these processes are proposed.
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页码：277 / 296
页数：20
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