Poly[[μ4-bis(4-pyridylcarbonyl)piperazine-κ4N:N′:O:O′]bis(thiocyanato-κN)cobalt(II)]

被引：0
|
作者：
Wilseck, Zachary M. [1 ]
LaDuca, Robert L. [1 ]
机构：
[1] Michigan State Univ, Lyman Briggs Coll, Dept Chem, E Lansing, MI 48825 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
D O I：
10.1107/S160053681001915X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Co(NCS)(2)(C16H16N4O2)](n), the octahedrally coordinated Co-II ion lies on a crystallographic inversion center, with trans isothiocyanate ligands. Pyridyl N-donor atoms and formyl O-donor atoms from exotetradentate bis(4-pyridylcarbonyl)piperazine (4-bpfp) ligands link the Co(NCS)(2) units into a [Co(NCS)(2)(4-bpfp)](n) coordination polymer layer that is oriented parallel to (101). The layers stack along [010] to construct the pseudo-three-dimensional structure.
引用
收藏
页码：M713 / U1120
页数：10
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