Novel, efficient and stereospecific synthesis of xylo-(2R,3S,4S)-phytosphingosine and threo-(2R,3R)-sphingosine

被引：22
|
作者：
Raghavan, S [1 ]
Rajender, A [1 ]
Yadav, JS [1 ]
机构：
[1] Indian Inst Chem Technol, Organ Div 1, Hyderabad 500007, Andhra Pradesh, India
来源：
TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 14期
关键词：
D O I：
10.1016/S0957-4166(03)00427-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The stereo- and regioselective elaboration of a bromohydrin from an olefinic precursor and Pummerer ene reaction for carbon-carbon bond formation are the key steps in a novel and flexible synthesis of xylo-phytosphingosine and threo-sphingosine. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2093 / 2099
页数：7
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